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@article{Coates:2019:10.1002/anie.201906825,
author = {Coates, G and Tan, HY and Kalff, C and White, A and Crimmin, MR},
doi = {10.1002/anie.201906825},
journal = {Angewandte Chemie - International Edition},
pages = {12514--12518},
title = {Defluorosilylation of industrially relevant fluoroolefins using nucleophilic silicon reagents},
url = {http://dx.doi.org/10.1002/anie.201906825},
volume = {58},
year = {2019}
}

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TY  - JOUR
AB  - A number of new magnesium and lithium silyl reagents were prepared and shown to be outstanding nucleophiles in reactions with industrially relevant fluoroolefins. These reactions result in a net transformation of either sp2 or sp3 C-F bonds into C-Si bonds by two modes of nucleophilic attack (SNV or SN2'). The methods are mild, proceeding with high chemo- and regioselectivity. Mechanistic pathways are described that lead to new substitution patterns from HFO-1234yf, HFO-1234ze and HFO-1336mzz, previously inaccessible by transition metal catalysed defluorosilylation routes.
AU  - Coates,G
AU  - Tan,HY
AU  - Kalff,C
AU  - White,A
AU  - Crimmin,MR
DO  - 10.1002/anie.201906825
EP  - 12518
PY  - 2019///
SN  - 1433-7851
SP  - 12514
TI  - Defluorosilylation of industrially relevant fluoroolefins using nucleophilic silicon reagents
T2  - Angewandte Chemie - International Edition
UR  - http://dx.doi.org/10.1002/anie.201906825
UR  - https://www.ncbi.nlm.nih.gov/pubmed/31245895
UR  - http://hdl.handle.net/10044/1/71022
VL  - 58
ER  -

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Professor Mark R. Crimmin

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