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@article{Sheldon:2021:10.26434/chemrxiv.14687331.v1,
author = {Sheldon, D and Crimmin, M},
doi = {10.26434/chemrxiv.14687331.v1},
title = {Complete Deconstruction of SF6 by an Aluminium(I) Compound},
url = {http://dx.doi.org/10.26434/chemrxiv.14687331.v1},
year = {2021}
}

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TY  - JOUR
AB  - <jats:p><jats:bold>The room-temperature activation of SF<jats:sub>6</jats:sub>, a potent greenhouse gas, is reported using a monovalent aluminium(I) reagent to form well-defined aluminium(III) fluoride and aluminium(III) sulfide products. New reactions have been developed to utilise the aluminium(III) fluoride and aluminium(III) sulfide as a nucleophilic source of F<jats:sup>–</jats:sup> and S<jats:sup>2– </jats:sup>for a range of electrophiles. The overall reaction sequence results in the net transfer of fluorine or sulfur atoms from an environmentally detrimental gas to useful organic products.</jats:bold></jats:p>
AU  - Sheldon,D
AU  - Crimmin,M
DO  - 10.26434/chemrxiv.14687331.v1
PY  - 2021///
TI  - Complete Deconstruction of SF6 by an Aluminium(I) Compound
UR  - http://dx.doi.org/10.26434/chemrxiv.14687331.v1
ER  -

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Professor Mark R. Crimmin

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