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@article{Batuecas:2021:10.26434/chemrxiv-2021-ndmfl,
author = {Batuecas, M and Kong, R and White, A and Crimmin, M},
doi = {10.26434/chemrxiv-2021-ndmfl},
title = {Functionalization and Hydrogenation of Carbon Chains Derived from CO},
url = {http://dx.doi.org/10.26434/chemrxiv-2021-ndmfl},
year = {2021}
}

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TY  - JOUR
AB  - <jats:p>Selective reactions that combine H2, CO and organic electrophiles (aldehyde, ketones, isocyanide) to form hydrogenated C3 and C4 carbon chains are reported. These reactions proceed by CO homologation mediated by [W(CO)6] and an aluminum(I) reductant, followed by functionalization and hydrogenation of the chain ends. A combination of kinetics (rates, KIEs) and DFT calculations has been used to gain insight into a key step which involves hydrogenation of a metallocarbene intermediate. These findings expand the extremely small scope of systems that combine H2 and CO to make well-defined products with complete control over chain length and functionality.</jats:p>
AU  - Batuecas,M
AU  - Kong,R
AU  - White,A
AU  - Crimmin,M
DO  - 10.26434/chemrxiv-2021-ndmfl
PY  - 2021///
TI  - Functionalization and Hydrogenation of Carbon Chains Derived from CO
UR  - http://dx.doi.org/10.26434/chemrxiv-2021-ndmfl
ER  -

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