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BibTex format

@article{Batuecas:2022:10.1002/anie.202202241,
author = {Batuecas, M and Kong, RY and White, AJP and Crimmin, MR},
doi = {10.1002/anie.202202241},
journal = {Angewandte Chemie International Edition},
title = {Functionalization and hydrogenation of carbon chains derived from CO},
url = {http://dx.doi.org/10.1002/anie.202202241},
volume = {61},
year = {2022}
}

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TY  - JOUR
AB  - Selective reactions that combine H 2 , CO and organic electrophiles (aldehyde, ketones, isocyanide) to form hydrogenated C 3 and C 4 carbon chains are reported. These reactions proceed by CO homologation mediated by [W(CO) 6 ] and an aluminum(I) reductant, followed by functionalization and hydrogenation of the chain ends. A combination of kinetics (rates, KIEs) and DFT calculations has been used to gain insight into a key step which involves hydrogenation of a metallocarbene intermediate. These findings expand the extremely small scope of systems that combine H 2 and CO to make well-defined products with complete control over chain length and functionality.
AU  - Batuecas,M
AU  - Kong,RY
AU  - White,AJP
AU  - Crimmin,MR
DO  - 10.1002/anie.202202241
PY  - 2022///
SN  - 1433-7851
TI  - Functionalization and hydrogenation of carbon chains derived from CO
T2  - Angewandte Chemie International Edition
UR  - http://dx.doi.org/10.1002/anie.202202241
UR  - https://www.ncbi.nlm.nih.gov/pubmed/35225403
UR  - https://onlinelibrary.wiley.com/doi/10.1002/anie.202202241
UR  - http://hdl.handle.net/10044/1/95856
VL  - 61
ER  -

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Professor Mark R. Crimmin

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