Imperial College London
Portrait Picture

Professor Mark R. Crimmin

Faculty of Natural Sciences, Department of Chemistry

Professor of Organometallic Chemistry
 
 
 
//

Contact

 

+44 (0)20 7594 2846m.crimmin Website

 
 
//

Location

 

501NMolecular Sciences Research HubWhite City Campus

//

Summary

 

Publications

Citation

BibTex format

@article{Crimmin:2017:10.1002/anie.201709072,
author = {Crimmin, MR and Hicken, A and White, AJP},
doi = {10.1002/anie.201709072},
journal = {Angewandte Chemie International Edition},
pages = {15127--15130},
title = {Selective Reduction of CO2 to a Formate Equivalent with Heterobimetallic Gold---Copper Hydride Complexes.},
url = {http://dx.doi.org/10.1002/anie.201709072},
volume = {56},
year = {2017}
}
Download

RIS format (EndNote, RefMan)

TY  - JOUR
AB  - A series of heterobimetallic complexes containing 3-center,2-electron Au-H-Cu bonds have been prepared from addition of a parent gold hydride to a bent d10 copper(I) fragment. These highly unusual heterobimetallic complexes represent a missing link in the widely investigated series of neutral and cationic coinage metal hydride complexes containing Cu-H-Cu and M-H-M+ moieties (M = Cu, Ag). The well-defined heterobimetallic hydride complexes act as pre-catalysts for the conversion of CO2 to HCO2Bpin using HBpin as a reductant. The selectivity of the heterobimetallic complexes for the catalytic production of a formate equivalent surpasses that of the parent monomeric group 11 complexes.
AU  - Crimmin,MR
AU  - Hicken,A
AU  - White,AJP
DO  - 10.1002/anie.201709072
EP  - 15130
PY  - 2017///
SN  - 1521-3757
SP  - 15127
TI  - Selective Reduction of CO2 to a Formate Equivalent with Heterobimetallic Gold---Copper Hydride Complexes.
T2  - Angewandte Chemie International Edition
UR  - http://dx.doi.org/10.1002/anie.201709072
UR  - http://hdl.handle.net/10044/1/51851
VL  - 56
ER  -
Download