Imperial College London
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Professor Mark R. Crimmin

Faculty of Natural Sciences, Department of Chemistry

Professor of Organometallic Chemistry
 
 
 
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Contact

 

+44 (0)20 7594 2846m.crimmin Website

 
 
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Location

 

501NMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Crimmin:2017:10.1002/ange.201706378,
author = {Crimmin, MR and Chen, W and Hooper, TN and White, AJO},
doi = {10.1002/ange.201706378},
journal = {Angewandte Chemie},
pages = {12861--12865},
title = {Palladium-Catalysed Carbon-Fluorine and Carbon-Hydrogen Bond Alumination of Fluoroarenes and Heteroarenes},
url = {http://dx.doi.org/10.1002/ange.201706378},
volume = {129},
year = {2017}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - Through serendipitous discovery, a palladium bis(phosphine) complex was identified as a catalyst for the selective transformation of sp2C−F and sp2C−H bonds of fluoroarenes and heteroarenes to sp2C−Al bonds (19 examples, 1mol % Pd loading). The carbon–fluorine bond functionalization reaction is highly selective for the formation of organoaluminium products in preference to hydrodefluorination products (selectivity=4.4:1 to 27:1). Evidence is presented for a tandem catalytic process in which hydrodefluorination is followed by sp2C−H alumination.
AU  - Crimmin,MR
AU  - Chen,W
AU  - Hooper,TN
AU  - White,AJO
DO  - 10.1002/ange.201706378
EP  - 12865
PY  - 2017///
SN  - 1521-3757
SP  - 12861
TI  - Palladium-Catalysed Carbon-Fluorine and Carbon-Hydrogen Bond Alumination of Fluoroarenes and Heteroarenes
T2  - Angewandte Chemie
UR  - http://dx.doi.org/10.1002/ange.201706378
UR  - http://hdl.handle.net/10044/1/51850
VL  - 129
ER  -
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