Imperial College London
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ProfessorMartinHeeney

Faculty of Natural Sciences, Department of Chemistry

Professor of Organic Materials
 
 
 
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Contact

 

+44 (0)20 7594 1248m.heeney Website

 
 
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Location

 

401GMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Aniés:2022:10.1016/j.polymer.2021.124481,
author = {Aniés, F and Qiao, Z and Nugraha, MI and Basu, A and Anthopoulos, TD and Gasparini, N and Heeney, M},
doi = {10.1016/j.polymer.2021.124481},
journal = {Polymer},
pages = {124481--124481},
title = {N-type polymer semiconductors incorporating para, meta, and ortho-carborane in the conjugated backbone},
url = {http://dx.doi.org/10.1016/j.polymer.2021.124481},
volume = {240},
year = {2022}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - We report on three novel n-type conjugated polymer semiconductors incorporating carborane in the polymer backbone and demonstrate their applicability in optoelectronic devices. Comparing the optoelectronic properties of para-, meta-, and ortho-carborane isomers revealed similar energetic characteristics between the different polymers, with the carborane unit acting as a “conjugation breaker”, confining electron delocalisation to the conjugated moieties. The fabrication of all-polymer organic photovoltaic (OPV) devices and thin-film transistors (TFTs) revealed some differences in device performance between the polymers, with the meta-carborane based polymer exhibiting superior performance in both OPV and TFT devices.
AU  - Aniés,F
AU  - Qiao,Z
AU  - Nugraha,MI
AU  - Basu,A
AU  - Anthopoulos,TD
AU  - Gasparini,N
AU  - Heeney,M
DO  - 10.1016/j.polymer.2021.124481
EP  - 124481
PY  - 2022///
SN  - 0032-3861
SP  - 124481
TI  - N-type polymer semiconductors incorporating para, meta, and ortho-carborane in the conjugated backbone
T2  - Polymer
UR  - http://dx.doi.org/10.1016/j.polymer.2021.124481
UR  - https://www.sciencedirect.com/science/article/pii/S0032386121011046?via%3Dihub
UR  - http://hdl.handle.net/10044/1/94113
VL  - 240
ER  -
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