Imperial College London
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DrMaxieRoessler

Faculty of Natural Sciences, Department of Chemistry

Reader in EPR Spectroscopy
 
 
 
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Contact

 

+44 (0)20 7594 9861m.roessler Website

 
 
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Location

 

301AMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Cirulli:2021:10.1002/anie.202103596,
author = {Cirulli, M and Salvadori, E and Zhang, Z-H and Dommett, M and Tuna, F and Bamberger, H and Lewis, JEM and Kaur, A and Tizzard, GJ and van, Slageren J and Crespo-Otero, R and Goldup, SM and Roessler, MM},
doi = {10.1002/anie.202103596},
journal = {Angewandte Chemie International Edition},
pages = {16051--16058},
title = {Rotaxane Co-II complexes as field-induced single-ion magnets},
url = {http://dx.doi.org/10.1002/anie.202103596},
volume = {60},
year = {2021}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - Mechanically chelating ligands have untapped potential for the engineering of metal ion properties. Here we demonstrate this principle in the context of CoII-based single-ion magnets. Using multi-frequency EPR, susceptibility and magnetization measurements we found that these complexes show some of the highest zero field splittings reported for five-coordinate CoII complexes to date. The predictable coordination behaviour of the interlocked ligands allowed the magnetic properties of their CoII complexes to be evaluated computationally a priori and our combined experimental and theoretical approach enabled us to rationalize the observed trends. The predictable magnetic behaviour of the rotaxane CoII complexes demonstrates that interlocked ligands offer a new strategy to design metal complexes with interesting functionality.
AU  - Cirulli,M
AU  - Salvadori,E
AU  - Zhang,Z-H
AU  - Dommett,M
AU  - Tuna,F
AU  - Bamberger,H
AU  - Lewis,JEM
AU  - Kaur,A
AU  - Tizzard,GJ
AU  - van,Slageren J
AU  - Crespo-Otero,R
AU  - Goldup,SM
AU  - Roessler,MM
DO  - 10.1002/anie.202103596
EP  - 16058
PY  - 2021///
SN  - 1433-7851
SP  - 16051
TI  - Rotaxane Co-II complexes as field-induced single-ion magnets
T2  - Angewandte Chemie International Edition
UR  - http://dx.doi.org/10.1002/anie.202103596
UR  - http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000661288400001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
UR  - https://onlinelibrary.wiley.com/doi/10.1002/anie.202103596
UR  - http://hdl.handle.net/10044/1/90257
VL  - 60
ER  -
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