Imperial College London

Prof Milo Shaffer

Faculty of Natural SciencesDepartment of Chemistry

Professor of Materials Chemistry
 
 
 
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Contact

 

+44 (0)20 7594 5825m.shaffer Website

 
 
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Assistant

 

Mr John Murrell +44 (0)20 7594 2845

 
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Location

 

M221Royal College of ScienceSouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@article{Thong:2018:10.1038/s41598-018-27557-0,
author = {Thong, A and Shaffer, M and Horsfield, AP},
doi = {10.1038/s41598-018-27557-0},
journal = {Scientific Reports},
title = {Rectification and negative differential resistance via orbital level pinning},
url = {http://dx.doi.org/10.1038/s41598-018-27557-0},
volume = {8},
year = {2018}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - A donor-acceptor system, 4-thiophenyl-azafulleroid (4TPA-C60), is investigated at the point of HOMO/LUMO resonance and beyond to understand how negative differential resistance (NDR) features may be observed in such systems. Our previous investigation showed that charge transfer between the occupied and unoccupied states at resonance hindered crossing of the HOMO and LUMO levels, thus preventing the formation of an NDR feature. In this work, it is shown that the negative differential resistance feature of 4TPA-C60 can be tailored based on the couplings at the metal/molecule interface. Ab initio calculations show that limited charge extraction from atomically sharp contacts results in a HOMO-LUMO pinning effect which delays the onset of the NDR feature. Subsequent unpinning of the states can only occur when additional charge extraction channels enter the bias window, highlighting an important role which non-frontier states play in charge transport. The proposed charge transfer mechanism is then exploited by introducing a fluorine atom into the C60 cage to tune the energies of the acceptor, and narrow the width of the current peak. These findings not only demonstrate the importance of the metal/molecule interface in the design of molecular electronic architectures but also serve to inform future design of molecular diodes and RTDs.
AU - Thong,A
AU - Shaffer,M
AU - Horsfield,AP
DO - 10.1038/s41598-018-27557-0
PY - 2018///
SN - 2045-2322
TI - Rectification and negative differential resistance via orbital level pinning
T2 - Scientific Reports
UR - http://dx.doi.org/10.1038/s41598-018-27557-0
UR - http://hdl.handle.net/10044/1/60503
VL - 8
ER -