Imperial College London

Prof. J. P. Martin Trusler

Faculty of EngineeringDepartment of Chemical Engineering

Professor of Thermophysics
 
 
 
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Contact

 

+44 (0)20 7594 5592m.trusler Website

 
 
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Assistant

 

Miss Jessica Baldock +44 (0)20 7594 5699

 
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Location

 

409ACE ExtensionSouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@article{Pan:2022:10.1016/j.fluid.2021.113364,
author = {Pan, Z and Trusler, JPM},
doi = {10.1016/j.fluid.2021.113364},
journal = {Fluid Phase Equilibria},
pages = {113364--113364},
title = {Interfacial tensions of systems comprising N2, 7 mass% KI (aq), decane and iododecane at elevated pressures and temperatures},
url = {http://dx.doi.org/10.1016/j.fluid.2021.113364},
volume = {556},
year = {2022}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - Interfacial tension (IFT) between reservoir fluids is an important property in enhanced oil recovery (EOR) and carbon geological storage (CGS). Quantitative knowledge of IFT is needed to support and assist the interpretation of multiphase flow and wetting behaviour in porous media and to facilitate numerical reservoir simulation. Iododecane and iodide-containing brines are common contrast agents in visualisation of multiphase flow in porous media by X-ray CT imaging. The effect of the introduced contrast agents on the IFT was studied in this work by means of pendant-drop experiments and modelling with the density-gradient theory. We report experimental IFTs between N2, 7 mass% KI (aq), and decane-iododecane mixtures with various iododecane mass fractions at temperatures from 298 K to 353 K and pressures from 1 MPa to 30 MPa. The IFTs between N2 and the liquid phases decrease with the increase of either pressure or temperature and increase with the increasing KI molality or iododecane mass fraction. The IFTs between H2O and decane-iododecane mixtures decrease with temperature or iododecane mass fraction and increase slightly with increasing pressure. The IFT data were modelled by means of the density-gradient theory coupled with the volume-translated Peng-Robinson equation of state. Empirical equations were also developed to correlate all of the measured data. A workflow was proposed for estimating the IFTs between gas, brine and the doped hydrocarbon systems based on the experimental and modelling work.
AU - Pan,Z
AU - Trusler,JPM
DO - 10.1016/j.fluid.2021.113364
EP - 113364
PY - 2022///
SN - 0378-3812
SP - 113364
TI - Interfacial tensions of systems comprising N2, 7 mass% KI (aq), decane and iododecane at elevated pressures and temperatures
T2 - Fluid Phase Equilibria
UR - http://dx.doi.org/10.1016/j.fluid.2021.113364
UR - https://www.sciencedirect.com/science/article/pii/S037838122100426X?via%3Dihub
UR - http://hdl.handle.net/10044/1/94110
VL - 556
ER -