Imperial College London

DrMatthewForeman

Faculty of Natural SciencesDepartment of Physics

Academic Visitor
 
 
 
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Contact

 

+44 (0)20 7594 7721matthew.foreman Website

 
 
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Location

 

642Blackett LaboratorySouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@article{Foreman:2015:10.1103/PhysRevLett.114.118001,
author = {Foreman, MR and Vollmer, F},
doi = {10.1103/PhysRevLett.114.118001},
journal = {Physical Review Letters},
title = {Optical Tracking of Anomalous Diffusion Kinetics in Polymer Microspheres},
url = {http://dx.doi.org/10.1103/PhysRevLett.114.118001},
volume = {114},
year = {2015}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - In this Letter we propose the use of whispering gallery mode resonance tracking as a label-free optical means to monitor diffusion kinetics in glassy polymer microspheres. Approximate solutions to the governing diffusion equations are derived for the case of slow relaxation and small Stefan number. Transduction of physical changes in the polymer, including formation of a rubbery layer, swelling, and dissolution, into detectable resonance shifts are described using a perturbative approach. Concrete examples of poly(methyl methacrylate) and polystyrene spheres in water are considered.
AU - Foreman,MR
AU - Vollmer,F
DO - 10.1103/PhysRevLett.114.118001
PY - 2015///
SN - 0031-9007
TI - Optical Tracking of Anomalous Diffusion Kinetics in Polymer Microspheres
T2 - Physical Review Letters
UR - http://dx.doi.org/10.1103/PhysRevLett.114.118001
UR - http://hdl.handle.net/10044/1/40683
VL - 114
ER -