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BibTex format

@article{Schrecker:2023:10.1039/d2re00271j,
author = {Schrecker, L and Dickhaut, J and Holtze, C and Staehle, P and Vranceanu, M and Hellgardt, K and Hii, KKM},
doi = {10.1039/d2re00271j},
journal = {Reaction Chemistry and Engineering},
pages = {41--46},
title = {Discovery of unexpectedly complex reaction pathways for the Knorr pyrazole synthesis via transient flow},
url = {http://dx.doi.org/10.1039/d2re00271j},
volume = {8},
year = {2023}
}

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TY  - JOUR
AB  - Kinetic data for reactions between phenyl hydrazine and 1,3-diketones (Knorr pyrazole synthesis) were acquired by using transient flow methods. Supported by further spectroscopic and mass spectrometry data, a microkinetic model was subsequently constructed, which provided new insights into the mechanism, including autocatalysis and the involvement of an unexpected reaction intermediate. During this work, a novel reactant stoichiometry transient flow methodology was demonstrated, allowing the robustness of these models to be asserted.
AU  - Schrecker,L
AU  - Dickhaut,J
AU  - Holtze,C
AU  - Staehle,P
AU  - Vranceanu,M
AU  - Hellgardt,K
AU  - Hii,KKM
DO  - 10.1039/d2re00271j
EP  - 46
PY  - 2023///
SN  - 2058-9883
SP  - 41
TI  - Discovery of unexpectedly complex reaction pathways for the Knorr pyrazole synthesis via transient flow
T2  - Reaction Chemistry and Engineering
UR  - http://dx.doi.org/10.1039/d2re00271j
UR  - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000857596600001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=a2bf6146997ec60c407a63945d4e92bb
UR  - https://pubs.rsc.org/en/content/articlelanding/2023/re/d2re00271j
UR  - http://hdl.handle.net/10044/1/109977
VL  - 8
ER  -

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Professor King Kuok (Mimi) Hii

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