Imperial College London

Dr Paul Boldrin

Faculty of EngineeringDepartment of Earth Science & Engineering

Research Associate
 
 
 
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Contact

 

+44 (0)20 7594 9695p.boldrin

 
 
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Location

 

3.50Royal School of MinesSouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@inproceedings{Stevenson:2019:10.1149/09101.1761ecst,
author = {Stevenson, GR and Boldrin, P and Brandon, NP},
doi = {10.1149/09101.1761ecst},
pages = {1761--1770},
title = {Liquid-based synthesis of nickel- And lanthanum- co-doped strontium titanates for use as anodes in all-ceramic solid oxide fuel cell anodes},
url = {http://dx.doi.org/10.1149/09101.1761ecst},
year = {2019}
}

RIS format (EndNote, RefMan)

TY  - CPAPER
AB - Nickel- lanthanum- co-doped compositions of strontium titanate have been synthesized and characterized by a scaleable liquid-based synthesis that may offer an alternative to conventional solid-state synthesis. La0.52Sr0.28Ti0.94Ni0.06O3 is synthesized from soluble precursors followed by calcination in air. The materials can be made phase pure at temperatures as low as 1250°C, as highlighted by X-ray diffraction, and nickel exsolves in hydrogen in the same way as solid-state-synthesized materials. The particle size can be varied by calcination temperature and ball milling between 2 µm and 20 µm. The material is then measured electrochemically by electrochemical impedance spectroscopy and 4-point DC conductivity. A reduction in particle size from 20 µm to 9 µm results in a large improvement in impedance response measured.
AU - Stevenson,GR
AU - Boldrin,P
AU - Brandon,NP
DO - 10.1149/09101.1761ecst
EP - 1770
PY - 2019///
SN - 1938-6737
SP - 1761
TI - Liquid-based synthesis of nickel- And lanthanum- co-doped strontium titanates for use as anodes in all-ceramic solid oxide fuel cell anodes
UR - http://dx.doi.org/10.1149/09101.1761ecst
ER -