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@article{Turnell-Ritson:2018:10.1039/c8sc03110j,
author = {Turnell-Ritson, RC and Sapsford, JS and Cooper, RT and Lee, SS and Foldes, T and Hunt, PA and Papai, I and Ashley, AE},
doi = {10.1039/c8sc03110j},
journal = {Chemical Science},
pages = {8716--8722},
title = {Base-induced reversible H-2 addition to a single Sn(II) centre},
url = {http://dx.doi.org/10.1039/c8sc03110j},
volume = {9},
year = {2018}
}

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TY  - JOUR
AB  - A range of amines catalyse the oxidative addition (OA) of H2 to [(Me3Si)2CH]2Sn (1), forming [(Me3Si)2CH]2SnH2 (2). Experimental and computational studies point to ‘frustrated Lewis pair’ mechanisms in which 1 acts as a Lewis acid and involve unusual late transition states; this is supported by the observation of a kinetic isotope effect Image ID:c8sc03110j-t1.gif for Et3N. When DBU is used the energetics of H2 activation are altered, allowing an equilibrium between 1, 2 and adduct [1·DBU] to be established, thus demonstrating reversible oxidative addition/reductive elimination (RE) of H2 at a single main group centre.
AU  - Turnell-Ritson,RC
AU  - Sapsford,JS
AU  - Cooper,RT
AU  - Lee,SS
AU  - Foldes,T
AU  - Hunt,PA
AU  - Papai,I
AU  - Ashley,AE
DO  - 10.1039/c8sc03110j
EP  - 8722
PY  - 2018///
SN  - 2041-6520
SP  - 8716
TI  - Base-induced reversible H-2 addition to a single Sn(II) centre
T2  - Chemical Science
UR  - http://dx.doi.org/10.1039/c8sc03110j
UR  - http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000451533000011&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
UR  - http://hdl.handle.net/10044/1/65377
VL  - 9
ER  -

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