Imperial College London
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Professor Philip J. Parsons

Faculty of Natural Sciences, Department of Chemistry

Senior Research Investigator
 
 
 
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Contact

 

p.parsons

 
 
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Location

 

110EMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Barrett:2016:10.1021/acs.orglett.6b00533,
author = {Barrett, AGM and Elliott, D and Ma, T and Cookson, R and Parsons, P and Selmani, A},
doi = {10.1021/acs.orglett.6b00533},
journal = {Organic Letters},
pages = {1800--1803},
title = {Sequential Ketene Generation from Dioxane-4,6-dione-keto-dioxinones for the Synthesis of Terpenoid Resorcylates},
url = {http://dx.doi.org/10.1021/acs.orglett.6b00533},
volume = {18},
year = {2016}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - Trapping of the ketene generated from the thermolysis of 2-methyl-2-phenyl-1,3-dioxane-4,6-dione-ketodioxinoneat 50 °C with primary, secondary, or tertiary alcohols gave the corresponding dioxinone β-keto-esters in good yieldunder neutral conditions. These intermediates were converted by palladium(0)-catalyzed decarboxylative allyl migration andaromatization into the corresponding β-resorcylates. These transformations were applied to the syntheses of the natural products(±)-cannabiorcichromenic and (±)-daurichromenic acid.
AU  - Barrett,AGM
AU  - Elliott,D
AU  - Ma,T
AU  - Cookson,R
AU  - Parsons,P
AU  - Selmani,A
DO  - 10.1021/acs.orglett.6b00533
EP  - 1803
PY  - 2016///
SN  - 1523-7060
SP  - 1800
TI  - Sequential Ketene Generation from Dioxane-4,6-dione-keto-dioxinones for the Synthesis of Terpenoid Resorcylates
T2  - Organic Letters
UR  - http://dx.doi.org/10.1021/acs.orglett.6b00533
UR  - http://hdl.handle.net/10044/1/30950
VL  - 18
ER  -
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