Imperial College London
Alternate

DrPhilipMiller

Faculty of Natural Sciences, Department of Chemistry

Reader in Applied Synthesis
 
 
 
//

Contact

 

philip.miller Website

 
 
//

Location

 

501kMolecular Sciences Research HubWhite City Campus

//

Summary

 

Publications

Citation

BibTex format

@article{Miller:2019:10.1039/c9cc01496a,
author = {Miller, P and Apps, S and Long, N},
doi = {10.1039/c9cc01496a},
journal = {Chemical Communications},
pages = {6579--6582},
title = {Cobalt(-I) triphos dinitrogen complexes: activation and silyl-functionalisation of N2},
url = {http://dx.doi.org/10.1039/c9cc01496a},
volume = {55},
year = {2019}
}
Download

RIS format (EndNote, RefMan)

TY  - JOUR
AB  - The cobalt dinitrogen complexes [{(EP3Ph)Co(μ-N2)}2Mg(THF)4], with triphos ligand scaffolds (EP3Ph, E = N or CMe), were prepared via two electron reductions of the Co(I) precursors [CoCl(EP3Ph)]. Both complexes showed high degrees of N2 activation owing to the formation of a rare M–NN–Mg–NN–M bridging-magnesium core. These systems showed further N2 functionalisation reactivity by silylation, forming silyldiazenido complexes [(EP3Ph)Co(NNSiMe3)].
AU  - Miller,P
AU  - Apps,S
AU  - Long,N
DO  - 10.1039/c9cc01496a
EP  - 6582
PY  - 2019///
SN  - 1359-7345
SP  - 6579
TI  - Cobalt(-I) triphos dinitrogen complexes: activation and silyl-functionalisation of N2
T2  - Chemical Communications
UR  - http://dx.doi.org/10.1039/c9cc01496a
UR  - http://hdl.handle.net/10044/1/70515
VL  - 55
ER  -
Download