Imperial College London
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Dr Becky Greenaway

Faculty of Natural Sciences, Department of Chemistry

Senior Lecturer
 
 
 
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Contact

 

r.greenaway Website

 
 
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Location

 

401CMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Egleston:2020:10.1002/anie.201914037,
author = {Egleston, BD and Luzyanin, KV and Brand, MC and Clowes, R and Briggs, ME and Greenaway, RL and Cooper, AI},
doi = {10.1002/anie.201914037},
journal = {Angewandte Chemie International Edition},
pages = {7362--7366},
title = {Controlling gas selectivity in molecular porous liquids by tuning the cage window size},
url = {http://dx.doi.org/10.1002/anie.201914037},
volume = {59},
year = {2020}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xeselective to CH4selective, which is understood using 129Xe, 1H, and pulsedfield gradient NMR spectroscopy.
AU  - Egleston,BD
AU  - Luzyanin,KV
AU  - Brand,MC
AU  - Clowes,R
AU  - Briggs,ME
AU  - Greenaway,RL
AU  - Cooper,AI
DO  - 10.1002/anie.201914037
EP  - 7366
PY  - 2020///
SN  - 1433-7851
SP  - 7362
TI  - Controlling gas selectivity in molecular porous liquids by tuning the cage window size
T2  - Angewandte Chemie International Edition
UR  - http://dx.doi.org/10.1002/anie.201914037
UR  - https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201914037
UR  - http://hdl.handle.net/10044/1/78934
VL  - 59
ER  -
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