Imperial College London

Dr Robert Hoye, FIMMM CEng CSci

Faculty of EngineeringDepartment of Materials

Honorary Senior Lecturer
 
 
 
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Contact

 

+44 (0)20 7594 6048r.hoye Website

 
 
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Location

 

2.27Royal School of MinesSouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@article{Hoye:2014:10.1002/aenm.201301544,
author = {Hoye, RLZ and Ehrler, B and Böhm, ML and MuñozRojas, D and Altamimi, RM and Alyamani, AY and Vaynzof, Y and Sadhanala, A and Ercolano, G and Greenham, NC and Friend, RH and MacManusDriscoll, JL and Musselman, KP},
doi = {10.1002/aenm.201301544},
journal = {Advanced Energy Materials},
title = {Improved Open Circuit Voltage in ZnO–PbSe Quantum Dot Solar Cells by Understanding and Reducing Losses Arising from the ZnO Conduction Band Tail},
url = {http://dx.doi.org/10.1002/aenm.201301544},
volume = {4},
year = {2014}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - <jats:p>Colloidal quantum dot solar cells (CQDSCs) are attracting growing attention owing to significant improvements in efficiency. However, even the best depletedheterojunction CQDSCs currently display opencircuit voltages (<jats:italic>V</jats:italic><jats:sub>OC</jats:sub>s) at least 0.5 V below the voltage corresponding to the bandgap. We find that the tail of states in the conduction band of the metal oxide layer can limit the achievable device efficiency. By continuously tuning the zinc oxide conduction band position via magnesium doping, we probe this critical loss pathway in ZnO–PbSe CQDSCs and optimize the energetic position of the tail of states, thereby increasing both the <jats:italic>V</jats:italic><jats:sub>OC</jats:sub> (from 408 mV to 608 mV) and the device efficiency.</jats:p>
AU - Hoye,RLZ
AU - Ehrler,B
AU - Böhm,ML
AU - MuñozRojas,D
AU - Altamimi,RM
AU - Alyamani,AY
AU - Vaynzof,Y
AU - Sadhanala,A
AU - Ercolano,G
AU - Greenham,NC
AU - Friend,RH
AU - MacManusDriscoll,JL
AU - Musselman,KP
DO - 10.1002/aenm.201301544
PY - 2014///
SN - 1614-6832
TI - Improved Open Circuit Voltage in ZnO–PbSe Quantum Dot Solar Cells by Understanding and Reducing Losses Arising from the ZnO Conduction Band Tail
T2 - Advanced Energy Materials
UR - http://dx.doi.org/10.1002/aenm.201301544
VL - 4
ER -