Imperial College London

Prof Rob Law

Faculty of Natural SciencesDepartment of Chemistry

Professor of Biological Materials
 
 
 
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Contact

 

+44 (0)20 7594 5860r.law Website

 
 
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Location

 

207GMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Jia:2018:10.1002/anie.201800875,
author = {Jia, J and White, ER and Clancy, AJ and Rubio, N and Suter, T and Miller, TS and McColl, K and McMillan, PF and Brázdová, V and Corà, F and Howard, CA and Law, RV and Mattevi, C and Shaffer, MSP},
doi = {10.1002/anie.201800875},
journal = {Angewandte Chemie},
pages = {12656--12660},
title = {Fast exfoliation and functionalisation of two-dimensional crystalline carbon nitride by framework charging},
url = {http://dx.doi.org/10.1002/anie.201800875},
volume = {57},
year = {2018}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - Two-dimensional (2D) layered graphitic carbon nitride (gCN) nanosheets offer intriguing electronic and chemical properties. However, the exfoliation and functionalisation of gCN for specific applications remain challenging. We report a scalable one-pot reductive method to produce solutions of single- and few-layer 2D gCN nanosheets with excellent stability in a high mass yield (35 %) from polytriazine imide. High-resolution imaging confirmed the intact crystalline structure and identified an AB stacking for gCN layers. The charge allows deliberate organic functionalisation of dissolved gCN, providing a general route to adjust their properties.
AU - Jia,J
AU - White,ER
AU - Clancy,AJ
AU - Rubio,N
AU - Suter,T
AU - Miller,TS
AU - McColl,K
AU - McMillan,PF
AU - Brázdová,V
AU - Corà,F
AU - Howard,CA
AU - Law,RV
AU - Mattevi,C
AU - Shaffer,MSP
DO - 10.1002/anie.201800875
EP - 12660
PY - 2018///
SN - 1521-3757
SP - 12656
TI - Fast exfoliation and functionalisation of two-dimensional crystalline carbon nitride by framework charging
T2 - Angewandte Chemie
UR - http://dx.doi.org/10.1002/anie.201800875
UR - https://www.ncbi.nlm.nih.gov/pubmed/30095209
UR - https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201800875
UR - http://hdl.handle.net/10044/1/62231
VL - 57
ER -