Imperial College London
Alternate

Dr Silvia Diez-Gonzalez

Faculty of Natural Sciences, Department of Chemistry

Senior Lecturer
 
 
 
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Contact

 

+44 (0)20 7594 9699s.diez-gonzalez Website

 
 
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Location

 

401EMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Radtanajiravong:2019:10.1021/acsomega.9b01427,
author = {Radtanajiravong, L and Diez-Gonzalez, S},
doi = {10.1021/acsomega.9b01427},
journal = {ACS Omega},
pages = {12300--12307},
title = {Taming Brønsted acid reactivity: nucleophilic substitutions of propargylic alcohols with n-nucleophiles mediated by phosphorus-based Brønsted acid catalysts},
url = {http://dx.doi.org/10.1021/acsomega.9b01427},
volume = {4},
year = {2019}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - The activity of diethyl phosphite and diphenyl phosphate in propargylation reactionswith N-nucleophiles of varying basicity is presented. Careful choice of the reaction conditionsminimised undesired rearrangements and arylation processes, typical side reactions withBrønsted acid catalysis. These systems are compatible with technical solvents and presence ofair and they are also applicable to C-, O- and S-nucleophiles
AU  - Radtanajiravong,L
AU  - Diez-Gonzalez,S
DO  - 10.1021/acsomega.9b01427
EP  - 12307
PY  - 2019///
SN  - 2470-1343
SP  - 12300
TI  - Taming Brønsted acid reactivity: nucleophilic substitutions of propargylic alcohols with n-nucleophiles mediated by phosphorus-based Brønsted acid catalysts
T2  - ACS Omega
UR  - http://dx.doi.org/10.1021/acsomega.9b01427
UR  - http://hdl.handle.net/10044/1/71628
VL  - 4
ER  -
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