Imperial College London

ProfessorThomasAnthopoulos

Faculty of Natural SciencesDepartment of Physics

Visiting Professor
 
 
 
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Contact

 

+44 (0)20 7594 6669thomas.anthopoulos Website

 
 
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Assistant

 

Mrs Carolyn Dale +44 (0)20 7594 7579

 
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Location

 

1111Blackett LaboratorySouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@article{Pitsalidis:2016:10.1039/c6tc00238b,
author = {Pitsalidis, C and Pappa, AM and Hunter, S and Laskarakis, A and Kaimakamis, T and Payne, MM and Anthony, JE and Anthopoulos, TD and Logothetidis, S},
doi = {10.1039/c6tc00238b},
journal = {Journal of Materials Chemistry C},
pages = {3499--3507},
title = {High mobility transistors based on electrospray-printed small-molecule/polymer semiconducting blends},
url = {http://dx.doi.org/10.1039/c6tc00238b},
volume = {4},
year = {2016}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - Spray-coating techniques have recently emerged as especially effective approaches for the deposition of small semiconducting molecules toward the fabrication of organic field-effect transistors (OFETs). Despite the promising mobility values and the industrial implementation capability of such techniques, the resultant devices still face challenges in terms of morphology control and performance variation. In this work, the efficient process control of electrostatic spraying deposition (ESD) and the excellent film forming properties of polymer:small molecule blends were successfully combined to develop reliable and high performance transistors. Specifically, a highly efficient blended system of 2,8-difluoro-5,11-bis(triethylsilylethynyl)-anthradithiophene (diF-TES-ADT) and poly(triarylamine) (PTAA) was employed in order to realize top-gate OFETs under ambient conditions, both on rigid and on flexible substrates. The films revealed extensive crystallization and microstructural organization implying distinct phase separation in the electrosprayed blend. Furthermore, we investigated the effect of processing temperature on film continuity and the presence of grain boundaries. Remarkably, the electrosprayed OFETs exhibited field-effect mobilities as high as 1.7 cm2 V−1 s−1 and enhanced performance consistency when compared to conventional gas-sprayed transistors. Additionally, the transistors showed excellent electrical and environmental stability, indicative of the good interface quality and the self-encapsulation capability of the top-gate structure. These results highlight the great potential of electrohydrodynamic atomization techniques for implementation in large-area processing for OFET fabrication.
AU - Pitsalidis,C
AU - Pappa,AM
AU - Hunter,S
AU - Laskarakis,A
AU - Kaimakamis,T
AU - Payne,MM
AU - Anthony,JE
AU - Anthopoulos,TD
AU - Logothetidis,S
DO - 10.1039/c6tc00238b
EP - 3507
PY - 2016///
SN - 2050-7534
SP - 3499
TI - High mobility transistors based on electrospray-printed small-molecule/polymer semiconducting blends
T2 - Journal of Materials Chemistry C
UR - http://dx.doi.org/10.1039/c6tc00238b
UR - http://hdl.handle.net/10044/1/33625
VL - 4
ER -