Imperial College London

ProfessorThomasAnthopoulos

Faculty of Natural SciencesDepartment of Physics

Visiting Professor
 
 
 
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Contact

 

+44 (0)20 7594 6669thomas.anthopoulos Website

 
 
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Assistant

 

Mrs Carolyn Dale +44 (0)20 7594 7579

 
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Location

 

1111Blackett LaboratorySouth Kensington Campus

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Summary

 

Publications

Publication Type
Year
to

509 results found

Zhou L, Cao Z, Wahyudi W, Zhang J, Hwang J-Y, Cheng Y, Wang L, Cavallo L, Anthopoulos T, Sun Y-K, Alshareef HN, Ming Jet al., 2020, Electrolyte Engineering Enables High Stability and Capacity Alloying Anodes for Sodium and Potassium Ion Batteries, ACS ENERGY LETTERS, Vol: 5, Pages: 766-776, ISSN: 2380-8195

Journal article

Zheng X, Yuan S, Liu J, Yie J, Yuan F, Shen W-S, Yao K, Wei M, Zhou C, Song K, Zhang B-B, Lin Y, Hedhili MN, Wehbe N, Han Y, Sun H-T, Lu Z-H, Anthopoulos TD, Mohammed OF, Sargent EH, Liao L-S, Bakr OMet al., 2020, Chlorine Vacancy Passivation in Mixed Halide Perovskite Quantum Dots by Organic Pseudohalides Enables Efficient Rec. 2020 Blue Light-Emitting Diodes, ACS ENERGY LETTERS, Vol: 5, Pages: 793-798, ISSN: 2380-8195

Journal article

Barrit D, Cheng P, Darabi K, Tang M-C, Smilgies D-M, Liu SF, Anthopoulos TD, Zhao K, Amassian Aet al., 2020, Room-Temperature Partial Conversion of α-FAPbI<sub>3</sub> Perovskite Phase via PbI<sub>2</sub> Solvation Enables High-Performance Solar Cells, ADVANCED FUNCTIONAL MATERIALS, Vol: 30, ISSN: 1616-301X

Journal article

He Q, Shahid M, Jiao X, Gann E, Eisner F, Wu T, Fei Z, Anthopoulos TD, McNeill CR, Heeney MJet al., 2020, The crucial role of fluorine in fully alkylated ladder type carbazole based non-fullerene organic solar cells, ACS Applied Materials and Interfaces, Vol: 12, Pages: 9555-9562, ISSN: 1944-8244

Two fused ladder type non-fullerene acceptors, DTCCIC and DTCCIC-4F, based on an electron-donating alkylated dithienocyclopentacarbazole core flanked by electron-withdrawing non-fluorinated or fluorinated 1,1-dicyanomethylene-3-indanone (IC or IC-4F), are prepared and utilized in organic solar cells (OSCs). The two new molecules reveal planar structures and strong aggregation behavior, and fluorination is shown to red shift the optical band gap and down shift energy levels. OSCs based on DTCCIC-4F exhibit a power conversion efficiency of 12.6 %, much higher than that of DTCCIC based devices (6.2 %). Microstructural studies reveal that while both acceptors are highly crystalline, bulk heterojunction blends based on the non-fluorinated DTCCIC result in overly coarse domains, while blends based on the fluorinated DTCCIC-4F exhibit a more optimal nanoscale morphology. These results highlight the importance of end group fluorination in controlling molecular aggregation and miscibility.

Journal article

Zheng X, Hou Y, Bao C, Yin J, Yuan F, Huang Z, Song K, Liu J, Troughton J, Gasparini N, Zhou C, Lin Y, Xue D-J, Chen B, Johnston AK, Wei N, Hedhili MN, Wei M, Alsalloum AY, Maity P, Turedi B, Yang C, Baran D, Anthopoulos TD, Han Y, Lu Z-H, Mohammed OF, Gao F, Sargent EH, Bakr OMet al., 2020, Managing grains and interfaces via ligand anchoring enables 22.3%-efficiency inverted perovskite solar cells, NATURE ENERGY, Vol: 5, Pages: 131-140, ISSN: 2058-7546

Journal article

Georgiadou DG, Lin Y, Lim J, Ratnasingham S, McLachlan MA, Snaith HJ, Anthopoulos TDet al., 2020, High Responsivity and Response Speed Single‐Layer Mixed‐Cation Lead Mixed‐Halide Perovskite Photodetectors Based on Nanogap Electrodes Manufactured on Large‐Area Rigid and Flexible Substrates, Advanced Functional Materials, Vol: 30, Pages: 1909758-1909758, ISSN: 1616-301X

Journal article

Tang M-C, Fan Y, Barrit D, Chang X, Dang HX, Li R, Wang K, Smilgies D-M, Liu SF, De Wolf S, Anthopoulos TD, Zhao K, Amassian Aet al., 2020, Ambient blade coating of mixed cation, mixed halide perovskites without dripping: <i>in situ</i> investigation and highly efficient solar cells, Publisher: ROYAL SOC CHEMISTRY, Pages: 1095-1104, ISSN: 2050-7488

Conference paper

Firdaus Y, He Q, Lin Y, Nugroho FAA, Le Corre VM, Yengel E, Balawi AH, Seitkhan A, Laquai F, Langhammer C, Liu F, Heeney M, Anthopoulos TDet al., 2020, Novel wide-bandgap non-fullerene acceptors for efficient tandem organic solar cells, Publisher: ROYAL SOC CHEMISTRY, Pages: 1164-1175, ISSN: 2050-7488

Conference paper

Wadsworth A, Chen H, Thorley KJ, Cendra C, Nikolka M, Bristow H, Moser M, Salleo A, Anthopoulos TD, Sirringhaus H, McCulloch Iet al., 2020, Modification of Indacenodithiophene-Based Polymers and Its Impact on Charge Carrier Mobility in Organic Thin-Film Transistors, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Vol: 142, Pages: 652-664, ISSN: 0002-7863

Journal article

Hallani RK, Moser M, Bristow H, Jenart MVC, Faber H, Neophytou M, Yarali E, Paterson AF, Anthopoulos TD, McCulloch Iet al., 2020, Low-Temperature Cross-Linking Benzocyclobutene Based Polymer Dielectric for Organic Thin Film Transistors on Plastic Substrates, JOURNAL OF ORGANIC CHEMISTRY, Vol: 85, Pages: 277-283, ISSN: 0022-3263

Journal article

Troughton J, Neophytou M, Gasparini N, Seitkhan A, Isikgor FH, Song X, Lin Y-H, Liu T, Faber H, Yengel E, Kosco J, Oszajca MF, Hartmeier B, Rossier M, Luechinger NA, Tsetseris L, Snaith H, De Wolf S, Anthopoulos T, McCulloch I, Baran Det al., 2020, A universal solution processed interfacial bilayer enabling ohmic contact in organic and hybrid optoelectronic devices, ENERGY & ENVIRONMENTAL SCIENCE, Vol: 13, Pages: 268-276, ISSN: 1754-5692

Journal article

Chaudhry MU, Panidi J, Nam S, Smith A, Lim J, Tetzner K, Patsalas PA, Vourlias G, Sit W-Y, Firdaus Y, Heeney M, Bradley DDC, Anthopoulos TDet al., 2020, Polymer Light-Emitting Transistors With Charge-Carrier Mobilities Exceeding 1 cm<SUP>2</SUP> V<SUP>-1</SUP> s<SUP>-1</SUP>, ADVANCED ELECTRONIC MATERIALS, Vol: 6, ISSN: 2199-160X

Journal article

Firdaus Y, Anthopoulos TD, 2020, DEVICE PHYSICS IN ORGANIC SOLAR CELLS AND DRIFT-DIFFUSION SIMULATIONS, SOFT-MATTER THIN FILM SOLAR CELLS, Editors: Ren, Kan, Publisher: AMER INST PHYSICS, ISBN: 978-0-7354-2238-4

Book chapter

Kumar M, Georgiadou DG, Seitkhan A, Loganathan K, Yengel E, Faber H, Naphade D, Basu A, Anthopoulos TD, Asadi Ket al., 2019, Colossal Tunneling Electroresistance in Co-Planar Polymer Ferroelectric Tunnel Junctions, ADVANCED ELECTRONIC MATERIALS, ISSN: 2199-160X

Journal article

Costa JC, Pouryazdan A, Panidi J, Spina F, Anthopoulos TD, Liedke MO, Schneider C, Wagner A, Munzenrieder Net al., 2019, Flexible IGZO TFTs and their suitability for space applications, IEEE Journal of the Electron Devices Society, Vol: 7, Pages: 1182-1190, ISSN: 2168-6734

In this paper, low earth orbit radiation (LEO), temperature, and magnetic field conditions are mimicked to investigate the suitability of flexible InGaZnO transistors for lightweight space wearables. More specifically, the impacts of high energetic electron irradiation with fluences up to 10 12 e - /cm 2 , low operating temperatures down to 78 K and magnetic fields up to 11 mT are investigated. This simulates 278 h in LEO. The threshold voltage and mobility of transistors that were exposed to e - irradiation are found to shift by +(0.09 ± 0.05) V and -(0.6 ± 0.5) cm 2 V -1 s -1 . Subsequent low temperature exposure resulted in additional shifts of +0.38 V and -5.95 cm 2 V -1 s -1 for the same parameters. These values are larger than the ones obtained from non-irradiated reference samples. Conversely, the performance of the devices was observed not to be significantly affected by the magnetic fields. Finally, a Cascode amplifier presenting a voltage gain of 10.3 dB and a cutoff frequency of 1.2 kHz is demonstrated after the sample had been irradiated, cooled down, and exposed to the magnetic fields. If these notions are considered during the systems design, these devices can be used to unobtrusively integrate sensor systems into space suits.

Journal article

Seitkhan A, Neophytou M, Kirkus M, Abou-Hamad E, Hedhili MN, Yengel E, Firdaus Y, Faber H, Lin Y, Tsetseris L, McCulloch I, Anthopoulos TDet al., 2019, Use of the Phen-NaDPO:Sn(SCN)<sub>2</sub> Blend as Electron Transport Layer Results to Consistent Efficiency Improvements in Organic and Hybrid Perovskite Solar Cells, ADVANCED FUNCTIONAL MATERIALS, Vol: 29, ISSN: 1616-301X

Journal article

Nam S, Chaudhry MU, Tetzner K, Pearson C, Groves C, Petty MC, Anthopoulos TD, Bradley DDCet al., 2019, Efficient and Stable Solution-Processed Organic Light-Emitting Transistors Using a High-<i>k</i> Dielectric, ACS PHOTONICS, Vol: 6, Pages: 3159-3165, ISSN: 2330-4022

Journal article

Lin Y-H, Li W, Faber H, Seitkhan A, Hastas NA, Khim D, Zhang Q, Zhang X, Pliatsikas N, Tsetseris L, Patsalas PA, Bradley DDC, Huang W, Anthopoulos TDet al., 2019, Hybrid organic-metal oxide multilayer channel transistors with high operational stability, NATURE ELECTRONICS, Vol: 2, Pages: 587-595, ISSN: 2520-1131

Journal article

Chen H, Wadsworth A, Ma C, Nanni A, Zhang W, Nikolka M, Luci AMT, Perdigao LMA, Thorley KJ, Cendra C, Larson B, Rumbles G, Anthopoulos TD, Salleo A, Costantini G, Sirringhaus H, McCulloch Iet al., 2019, The Effect of Ring Expansion in Thienobenzo[<i>b</i>]indacenodithiophene Polymers for Organic Field-Effect Transistors, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Vol: 141, Pages: 18806-18813, ISSN: 0002-7863

Journal article

Han A, Aljarb A, Liu S, Li P, Ma C, Xue F, Lopatin S, Yang C-W, Huang J-K, Wan Y, Zhang X, Xiong Q, Huang K-W, Tung V, Anthopoulos TD, Li L-Jet al., 2019, Growth of 2H stacked WSe<sub>2</sub> bilayers on sapphire, NANOSCALE HORIZONS, Vol: 4, Pages: 1434-1442, ISSN: 2055-6756

Journal article

Neophytou M, De Bastiani M, Gasparini N, Aydin E, Ugur E, Seitkhan A, Moruzzi F, Choaie Y, Ramadan AJ, Troughton J, Hallani R, Savva A, Tsetseris L, Inal S, Baran D, Laquai F, Anthopoulos T, Snaith HJ, De Wolf S, McCulloch Iet al., 2019, Enhancing the Charge Extraction and Stability of Perovskite Solar Cells Using Strontium Titanate (SrTiO<sub>3</sub>) Electron Transport Layer, ACS APPLIED ENERGY MATERIALS, Vol: 2, Pages: 8090-8097, ISSN: 2574-0962

Journal article

Faber H, Anthopoulos TD, 2019, Adding a new layer to 'more than Moore', NATURE ELECTRONICS, Vol: 2, Pages: 497-498, ISSN: 2520-1131

Journal article

Lin Y, Adilbekova B, Firdaus Y, Yengel E, Faber H, Sajjad M, Zheng X, Yarali E, Seitkhan A, Bakr OM, El-Labban A, Schwingenschlogl U, Tung V, McCulloch I, Laquai F, Anthopoulos TDet al., 2019, 17% Efficient Organic Solar Cells Based on Liquid Exfoliated WS<sub>2</sub> as a Replacement for PEDOT:PSS, ADVANCED MATERIALS, Vol: 31, ISSN: 0935-9648

Journal article

Barrit D, Cheng P, Tang M-C, Wang K, Hoang D, Smilgies D-M, Liu SF, Anthopoulos TD, Zhao K, Amassian Aet al., 2019, Impact of the Solvation State of Lead Iodide on Its Two-Step Conversion to MAPbI<sub>3</sub>: An In Situ Investigation, ADVANCED FUNCTIONAL MATERIALS, Vol: 29, ISSN: 1616-301X

Journal article

Li Z, Li H, Jiang K, Ding D, Li J, Ma C, Jiang S, Wang Y, Anthopoulos TD, Shi Yet al., 2019, Self-Powered Perovskite/CdS Heterostructure Photodetectors, ACS APPLIED MATERIALS & INTERFACES, Vol: 11, Pages: 40204-40213, ISSN: 1944-8244

Journal article

He Q, Shahid M, Wu J, Jiao X, Eisner FD, Hodsden T, Fei Z, Anthopoulos TD, McNeill CR, Durrant JR, Heeney Met al., 2019, Fused Cyclopentadithienothiophene acceptor enables ultrahigh short‐circuit current and high efficiency >11% in as‐cast organic solar cells, Advanced Functional Materials, Vol: 29, Pages: 1-7, ISSN: 1616-301X

A new method to synthesize an electron‐rich building block cyclopentadithienothiophene (9H‐thieno‐[3,2‐b]thieno[2″,3″:4′,5′]thieno[2′,3′:3,4]cyclopenta[1,2‐d]thiophene, CDTT) via a facile aromatic extension strategy is reported. By combining CDTT with 1,1‐dicyanomethylene‐3‐indanone endgroups, a promising nonfullerene small molecule acceptor (CDTTIC) is prepared. As‐cast, single‐junction nonfullerene organic solar cells based on PFBDB‐T: CDTTIC blends exhibit very high short‐circuit currents up to 26.2 mA cm−2 in combination with power conversion efficiencies over 11% without any additional processing treatments. The high photocurrent results from the near‐infrared absorption of the CDTTIC acceptor and the well‐intermixed blend morphology of polymer donor PFBDB‐T and CDTTIC. This work demonstrates a useful fused ring extension strategy and promising solar cell results, indicating the great potential of the CDTT derivatives as electron‐rich building blocks for constructing high‐performance small molecule acceptors in organic solar cells.

Journal article

Lin Y-H, Huang W, Pattanasattayavong P, Lim J, Li R, Sakai N, Panidi J, Hong MJ, Ma C, Wei N, Wehbe N, Fei Z, Heeney M, Labram JG, Anthopoulos TD, Snaith HJet al., 2019, Deciphering photocarrier dynamics for tuneable high-performance perovskite-organic semiconductor heterojunction phototransistors, NATURE COMMUNICATIONS, Vol: 10, ISSN: 2041-1723

Journal article

Ray S, Panidi J, Mukhopadhay T, Salzner U, Anthopoulos TD, Patil Set al., 2019, Electrochemical stability and ambipolar charge transport in diketopyrrolopyrrole-based organic materials, ACS Applied Electronic Materials, Vol: 1, Pages: 2037-2046, ISSN: 2637-6113

An important strategy for realizing flexible complementary circuits with organic semiconductors is to achieve balanced ambipolar charge transport properties with reduced anisotropy. Here, we present a series of star-shaped diketopyrrolopyrrole (DPP)-based organic materials synthesized for improved intermolecular charge transport while retaining the ambipolar charge transport properties of their linear counterparts. Steady-state UV–visible spectroscopic studies confirm that the oligomers are highly aggregated in the thin film as evidenced from appearance of prominent vibronic features and red-shifted absorption bands. Ambipolar transport properties of these materials were verified in organic field-effect transistors (OFETs). The results show that the star-shaped DPP systems have the potential to outperform their linear counterparts in devices.

Journal article

Anthopoulos TD, 2019, Ultrathin channels make transistors go faster, NATURE MATERIALS, Vol: 18, Pages: 1033-1034, ISSN: 1476-1122

Journal article

Karuthedath S, Firdaus Y, Liang R-Z, Gorenflot J, Beaujuge PM, Anthopoulos TD, Laquai Fet al., 2019, Impact of Fullerene on the Photophysics of Ternary Small Molecule Organic Solar Cells, ADVANCED ENERGY MATERIALS, Vol: 9, ISSN: 1614-6832

Journal article

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