My research focus is the development and application of new geochemical and isotopic tracers in marine geochemistry, paleoceanography and paleoclimate, with particular focus on radiogenic isotope systems (Ar, Sr, Nd, Hf, Pb). Although these tracers have been widely used in solid-earth geochemistry, they represent a relatively new but promising suite of tracers in the low-temperature environment. I utilize them to decipher past changes in ocean circulation patterns, continental weathering, and ice sheet evolution on million-year to millennial time scales. Below some selected projects I am working on.
If you are interested to join the MAGIC isotope geochemistry group at Imperial College London (for research experience as an undergraduate student, a PhD, or a postdoctoral research position), please do not hesitate to get in touch.
1) History of the Antarctic Ice Sheets - Looking Back Into the Future?
The East Antarctic Ice Sheet (EAIS) is up to 4 km thick, and covers an area larger than the United States. Together with the roughly eight times smaller West Antarctic Ice Sheet (WAIS), a water mass is locked up on Antarctica that if melted would be equivalent to a sea level rise of ~60 m.
From the study of marine sediments we know that today's situation on Antarctica with a stable EAIS and a potentially unstable WAIS is just a snapshot in the Cenozoic glacial history, which has been characterized by the transition from a largely ice-free "Greenhouse world" more than 50 million years ago, to the present "Icehouse world" with ice caps on both poles.
Photo credit: Peter Hollinger.
I am particularly interested in reconstructing the extent of the Antarctic ice sheet during times of elevated warmth in the past. The most vulnerable parts of the ice sheets today are the low-lying or marine-based areas of the West and East Antarctic ice sheet. Was this also the case in the past? Studying the chemical composition of coarse sand grains and fine clay can help us answer this question and provide valuable clues for the future. The chemical fingerprint of such detritus hosts information on where it was eroded from, in turn revealing the position of the eroding ice margin.
This research has been supported by the Kristian Gerhard Jebsen Foundation, the National Science Foundation, the NERC UK IODP, the European Comission (IRG), the Royal Society, and the Grantham Institute for Climate Change.
WILKES LAND IODP EXPEDITION 318
From 4 January to 9 March 2010 I was aboard the drill ship Joides Resolution on IODP expedition 318 to Wilkes Land, Antarctica.
I reported from this expedition in my blog: https://www2.imperial.ac.uk/blog/wilkeslandiodpexpedition/
We also had a professional videographer onboard, who produced weekly video summaries for Ocean Leadership, which can be found on YouTube: http://www.youtube.com/playlist?list=PL8AC7E48053CB639C
Check out our publications in Nature on 'Ice loss from the East Antarctic ice sheet during the late Pleistocene interglacials' and Nature Geoscience on 'Dynamic behaviour of the East Antarctic ice sheet during the Pliocene warmth'.
Another exciting project was the first deployment of the sea floor drill rig MeBo in the Amundsen Sea in 2017.
From January to March 2018 I sailed on IODP Expedition 374 to the Ross Sea to explore the history of the West Antarctic ice sheet and ocean-ice interaction throughout the Neogene.
Stay tuned for the first results from this exciting expedition.
2) The Ocean's Role in Climate Change Unraveled by Cold Water Corals
The deep ocean contains a large fraction of the carbon in the coupled ocean-atmosphere system. Therefore small changes in ocean circulation have the potential to profoundly affect the climate system. From the study of marine sediment cores we know that such changes happened in the past – some very rapidly and on short time-scales (decades), and others more gradually and on longer time-scales (millions of years).
Deep-sea corals offer two main advantages over sedimentary cores when trying to investigate recent and historical changes in the deep ocean: they can be dated radiometrically, and their skeletons record high–resolution information on past environmental conditions.
I use deep-sea corals to constrain past water mass configurations and ventilation histories by comparing neodymium and lead isotope results with radiocarbon analyses on directly dated scleractinian corals. Despite the unique nature of cold water corals as climate recorders, their potential has not yet been fully realized.
To get some impression on deep-sea coral sampling in the Southern Ocean, check out the following link from a cruise I participated in in 2008 (NBP0805).
This research has been supported by the Leverhulme Trust, the National Science Foundation, the Natural Environment Research Council,the European Comission (IRG), and the Grantham Institute for Climate Change.
Check out some of our results on dynamic intermediate circulation in the deglacial North Atlantic and first results on Pb isotopes in Southern Ocean deep-sea corals.
3) Marine Biogeochemical Cycles of Trace Elements and Their Isotopes
Trace elements play an important role in the ocean as nutrients, as tracers of processes now and in the past, and as contaminants. Their biogeochemical cycling has direct implications for research in such diverse areas as the carbon cycle, climate change, ocean ecosystems and environmental contamination.
GEOTRACES (www.geotraces.org) is an international study of the global marine biogeochemical cycles of trace elements and their isotopes. Its mission is to identify pro cesses and quantify fluxes that control the distributions of key trace elements and their isotopes in the ocean, and to establish the sensitivity of these distributions to changing environmental conditions.
I co-organised the intercalibration phase of this program for Nd isotopes and rare earth elements (REE). Guidlines for sampling and analytical methods are available on the international GEOTRACES webpage (cookbook) and our two intercalibration papers got published in 2012 in Limnology and Oceanography Methods.
In 2010 the major field program kicked off, and we had the first UK GEOTRACES cruise (GA10) in the South Atlantic.
This research has been supported by the National Science Foundation and the Natural Environment Research Council.
Check out our publications on Nd isotopes in the North Atlantic along one of the Dutch sections (GA02) and our results on natural and anthropogenic Pb signatures in the Equatorial Atlantic from the second UK cruise (GA06) and a review paper on Nd isotopes comparing east and west Atlantic datasets and their palaeo implications.