Imperial College London


Faculty of Natural SciencesDepartment of Physics

Research Postgraduate







724Huxley BuildingSouth Kensington Campus





Publication Type

6 results found

Marin-Beloqui J, Zhang G, Guo J, Shaikh J, Wohrer T, Hosseini SM, Sun B, Shipp J, Auty AJ, Chekulaev D, Ye J, Chin Y-C, Sullivan MB, Mozer AJ, Kim J-S, Shoaee S, Clarke TMet al., 2022, Insight into the Origin of Trapping in Polymer/Fullerene Blends with a Systematic Alteration of the Fullerene to Higher Adducts, JOURNAL OF PHYSICAL CHEMISTRY C, Vol: 126, Pages: 2708-2719, ISSN: 1932-7447

Journal article

Park SY, Labanti C, Luke J, Chin YC, Kim JSet al., 2022, Organic bilayer photovoltaics for efficient indoor light harvesting, Advanced Energy Materials, Vol: 12, Pages: 1-10, ISSN: 1614-6832

Indoor organic photovoltaics (OPVs) are a potential niche application for organic semiconductors due to their strong and well-matched absorption with the emission of indoor lighting. However, due to extremely low photocurrent generation, the device parameters critical for efficient indoor OPVs differ from those under 1 Sun conditions. Herein, these critical device parameters—recombination loss and shunt resistance (Rsh)—are identified and it is demonstrated that bilayer OPVs are suitable for indoor PV applications. Compared to bulk-heterojunction (BHJ), the open-circuit voltage loss of bilayer devices under low light intensities is much smaller, consistent with a larger surface photovoltage response, indicating suppressed recombination losses. The bilayer devices show a higher fill factor at low light intensities, resulting from high Rsh afforded by the ideal interfacial contacts between the photoactive and the charge transport layers. The high Rsh enables bilayer devices to perform well without a light-soaking process. Finally, the charge carriers are extracted rapidly in bilayers, which are attributed to strongly suppressed trap states possibly induced by isolated domains and non-ideal interfacial contacts in BHJs. This study highlights the excellent suitability of bilayer OPVs for indoor applications and demonstrates the importance of device architecture and interfacial structures for efficient indoor OPVs.

Journal article

Chin Y-C, Daboczi M, Henderson C, Luke J, Kim J-Set al., 2022, Suppressing PEDOT:PSS doping-induced interfacial recombination loss in perovskite solar cells, ACS Energy Letters, Vol: 7, Pages: 560-568, ISSN: 2380-8195

PEDOT:PSS is widely used as a hole transport layer (HTL) in perovskite solar cells (PSCs) due to its facile processability, industrial scalability, and commercialization potential. However, PSCs utilizing PEDOT:PSS suffer from strong recombination losses compared to other organic HTLs. This results in lower open-circuit voltage (VOC) and power conversion efficiency (PCE). Most studies focus on doping PEDOT:PSS to improve charge extraction, but it has been suggested that a high doping level can cause strong recombination losses. Herein, we systematically dedope PEDOT:PSS with aqueous NaOH, raising its Fermi level by up to 500 meV, and optimize its layer thickness in p-i-n devices. A significant reduction of recombination losses at the dedoped PEDOT:PSS/perovskite interface is evidenced by a longer photoluminescence lifetime and higher magnitude of surface photovoltage, leading to an increased device VOC, fill factor, and PCE. These results provide insights into the relationship between doping level of HTLs and interfacial charge carrier recombination losses.

Journal article

Daboczi M, Ratnasingham SR, Mohan L, Pu C, Hamilton I, Chin Y-C, McLachlan MA, Kim J-Set al., 2021, Optimal Interfacial Band Bending Achieved by Fine Energy Level Tuning in Mixed-Halide Perovskite Solar Cells, ACS ENERGY LETTERS, Vol: 6, Pages: 3970-3981, ISSN: 2380-8195

Journal article

Dong Y, Nikolis VC, Talnack F, Chin Y-C, Benduhn J, Londi G, Kublitski J, Zheng X, Mannsfeld SCB, Spoltore D, Muccioli L, Li J, Blase X, Beljonne D, Kim J-S, Bakulin AA, D'Avino G, Durrant JR, Vandewal Ket al., 2020, Orientation dependent molecular electrostatics drives efficient charge generation in homojunction organic sol, Nature Communications, Vol: 11, ISSN: 2041-1723

Organic solar cells usually utilise a heterojunction between electron-donating (D) and electron-accepting (A) materials to split excitons into charges. However, the use of D-A blends intrinsically limits the photovoltage and introduces morphological instability. Here, we demonstrate that polycrystalline films of chemically identical molecules offer a promising alternative and show that photoexcitation of α-sexithiophene (α-6T) films results in efficient charge generation. This leads to α-6T based homojunction organic solar cells with an external quantum efficiency reaching up to 44% and an open-circuit voltage of 1.61 V. Morphological, photoemission, and modelling studies show that boundaries between α-6T crystalline domains with different orientations generate an electrostatic landscape with an interfacial energy offset of 0.4 eV, which promotes the formation of hybridised exciton/charge-transfer states at the interface, dissociating efficiently into free charges. Our findings open new avenues for organic solar cell design where material energetics are tuned through molecular electrostatic engineering and mesoscale structural control.

Journal article

Wu J, Lee J, Chin Y-C, Yao H, Cha H, Luke J, Hou J, Kim J-S, Durrant Jet al., 2020, Exceptionally low charge trapping enables highly efficient organic bulk heterojunction solar cells, Energy & Environmental Science, Vol: 13, Pages: 2422-2430, ISSN: 1754-5692

In this study, we investigate the underlying origin of the high performance of PM6:Y6 organic solar cells. Employing transient optoelectronic and photoemission spectroscopies, we find that this blend exhibits greatly suppressed charge trapping into electronic intra-bandgap tail states compared to other polymer/non-fullerene acceptor solar cells, attributed to lower energetic disorder. The presence of tail states is a key source of energetic loss in most organic solar cells, as charge carriers relax into these states, reducing the quasi-Fermi level splitting and therefore device VOC. DFT and Raman analyses indicate this suppression of tail state energetics disorder could be associated with a higher degree of conformational rigidity and uniformity for the Y6 acceptor. We attribute the origin of such conformational rigidity and uniformity of Y6 to the presence of the two alkyl side chains on the outer core that restricts end-group rotation by acting as a conformation locker. The resultant enhanced carrier dynamics and suppressed charge carrier trapping are proposed to be a key factor behind the high performance of this blend. Low energetic disorder is suggested to be a key factor enabling reasonably efficient charge generation in this low energy offset system. In the absence of either energetic disorder or a significant electronic energy offset, it is argued that charge separation in this system is primarily entropy driven. Nevertheless, photocurrent generation is still limited by slow hole transfer from Y6 to PM6, suggesting pathways for further efficiency improvement.

Journal article

This data is extracted from the Web of Science and reproduced under a licence from Thomson Reuters. You may not copy or re-distribute this data in whole or in part without the written consent of the Science business of Thomson Reuters.

Request URL: Request URI: /respub/WEB-INF/jsp/search-html.jsp Query String: respub-action=search.html&id=01430346&limit=30&person=true