TY - JOUR AB - Two-dimensional (2D) layered graphitic carbon nitride (gCN) nanosheets offer intriguing electronic and chemical properties. However, the exfoliation and functionalisation of gCN for specific applications remain challenging. We report a scalable one-pot reductive method to produce solutions of single- and few-layer 2D gCN nanosheets with excellent stability in a high mass yield (35 %) from polytriazine imide. High-resolution imaging confirmed the intact crystalline structure and identified an AB stacking for gCN layers. The charge allows deliberate organic functionalisation of dissolved gCN, providing a general route to adjust their properties. AU - Jia,J AU - White,ER AU - Clancy,AJ AU - Rubio,N AU - Suter,T AU - Miller,TS AU - McColl,K AU - McMillan,PF AU - Brázdová,V AU - Corà,F AU - Howard,CA AU - Law,RV AU - Mattevi,C AU - Shaffer,MSP DO - 10.1002/anie.201800875 EP - 12660 PY - 2018/// SN - 1521-3757 SP - 12656 TI - Fast exfoliation and functionalisation of two-dimensional crystalline carbon nitride by framework charging T2 - Angewandte Chemie UR - http://dx.doi.org/10.1002/anie.201800875 UR - https://www.ncbi.nlm.nih.gov/pubmed/30095209 UR - https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201800875 UR - http://hdl.handle.net/10044/1/62231 VL - 57 ER -