Citation

BibTex format

@article{Green:1996:10.1039/CC9960001563,
author = {Green, MJ and Britovsek, GJP and Cavell, KJ and Skelton, BW and White, AH},
doi = {10.1039/CC9960001563},
journal = {Chemical Communications},
pages = {1563--1564},
title = {Ethene insertion into a palladium-acetyl bond: Crystal structure of [Pd(CH<inf>2</inf>CH<inf>2</inf>COMe)(NC<inf>5</inf>H<inf>4</inf>CO <inf>2</inf>Me-2)(PPh<inf>3</inf>)]BF<inf>4</inf>, a novel reaction intermediate from the insertion process},
url = {http://dx.doi.org/10.1039/CC9960001563},
year = {1996}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - From the catalytic conversion of CO and ethene to polyketone with [Pd(Me)(NC5H4CO2Me-2)- (PPh3)]BF4 1, the reaction of ethene with [Pd(COMe)(NC5H4CO2Me-2)-(PPh 3)]BF4 2 yields a rare example of an isolable product from the insertion of an unstrained alkene into a Pd-acyl bond, and the crystal structure of [Pd(CH2CH2COMe)-(NC5H4CO 2Me-2)(PPh3)]BF4 3 showing a novel square-pyramidal intermediate with a weakly interacting oxygen in the apical position.
AU  - Green,MJ
AU  - Britovsek,GJP
AU  - Cavell,KJ
AU  - Skelton,BW
AU  - White,AH
DO  - 10.1039/CC9960001563
EP  - 1564
PY  - 1996///
SN  - 1359-7345
SP  - 1563
TI  - Ethene insertion into a palladium-acetyl bond: Crystal structure of [Pd(CH<inf>2</inf>CH<inf>2</inf>COMe)(NC<inf>5</inf>H<inf>4</inf>CO <inf>2</inf>Me-2)(PPh<inf>3</inf>)]BF<inf>4</inf>, a novel reaction intermediate from the insertion process
T2  - Chemical Communications
UR  - http://dx.doi.org/10.1039/CC9960001563
ER  -
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Prof. Dr. George Britovsek FRSC

Director MRes Catalysis & Engineering

Tel: +44 (0)20 7594 5863

Email: g.britovsek@imperial.ac.uk

Department of Chemistry
Imperial College London
Molecular Sciences Research Hub
White City Campus
80 Wood Lane
London W12 0BZ
United Kingdom