Imperial College London
Alternate

Professor DameJuliaHiggins

Faculty of Engineering, Department of Chemical Engineering

Emeritus Professor Distinguished Research Fellow
 
 
 
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Contact

 

+44 (0)20 7594 5565j.higgins

 
 
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Assistant

 

Mrs Sarah Payne +44 (0)20 7594 5567

 
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Location

 

337Roderic Hill BuildingSouth Kensington Campus

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Summary

 

Publications

Citation

BibTex format

@article{Pillay:2001:10.1002/1521-3900(200103)166:1<269::AID-MASY269>3.0.CO;2-7,
author = {Pillay, R and Higgins, JS and Arrighi, V and Kagunya, W},
doi = {10.1002/1521-3900(200103)166:1<269::AID-MASY269>3.0.CO;2-7},
journal = {Macromolecular Symposia},
pages = {269--276},
title = {Ester methyl group dynamics in the poly(methyl methacrylate) stereocomplex: A neutron scattering study},
url = {http://dx.doi.org/10.1002/1521-3900(200103)166:1<269::AID-MASY269>3.0.CO;2-7},
volume = {166},
year = {2001}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - Quasielastic neutron scattering was employed to investigate the ester methyl group dynamics of isotactic poly(methyl methacrylate) (PMMA) and atactic PMMA when incorporated into the PMMA stereocomplex. The data were analysed using the Rotational Rate Distribution Model. The results were compared to those for atactic PMMA and a non-complexed blend of isotactic PMMA and atactic PMMA. The activation energy, attempt frequency and variance values of the isotactic PMMA ester methyl group in the stereocomplex suggests that this group is involved in an interaction within the stereocomplex.
AU  - Pillay,R
AU  - Higgins,JS
AU  - Arrighi,V
AU  - Kagunya,W
DO  - 10.1002/1521-3900(200103)166:1<269::AID-MASY269>3.0.CO;2-7
EP  - 276
PY  - 2001///
SN  - 1022-1360
SP  - 269
TI  - Ester methyl group dynamics in the poly(methyl methacrylate) stereocomplex: A neutron scattering study
T2  - Macromolecular Symposia
UR  - http://dx.doi.org/10.1002/1521-3900(200103)166:1<269::AID-MASY269>3.0.CO;2-7
VL  - 166
ER  -
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