Imperial College London
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Dr James A Bull

Faculty of Natural Sciences, Department of Chemistry

Reader in Synthetic Chemistry
 
 
 
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Contact

 

+44 (0)20 7594 5811j.bull Website

 
 
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Location

 

501bMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Bull:2023:10.1080/10426507.2023.2175827,
author = {Bull, J},
doi = {10.1080/10426507.2023.2175827},
journal = {Phosphorus Sulfur and Silicon and the Related Elements},
pages = {471--477},
title = {Synthesis of aza-S(VI) motifs},
url = {http://dx.doi.org/10.1080/10426507.2023.2175827},
volume = {198},
year = {2023}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - Sulfoximines and sulfonimidamides are of interest as design options for medicinal chemists. This article describes the development of methods for the synthesis of sulfoximines by metal-free NH-transfer to sulfoxides, and NH/O transfer to sulfides, using convenient sources of ammonia and hypervalent iodine reagents. Similarly, sulfonimidamides are prepared from sulfenamides. Methods for the preparation of enantioenriched sulfonimidoyl fluorides are also described, as is their stereospecific reactions with amines and Grignard reagents. This work was presented at the 29th International Symposium on the Organic Chemistry of Sulfur (Guelph, July 2022).
AU  - Bull,J
DO  - 10.1080/10426507.2023.2175827
EP  - 477
PY  - 2023///
SN  - 1042-6507
SP  - 471
TI  - Synthesis of aza-S(VI) motifs
T2  - Phosphorus Sulfur and Silicon and the Related Elements
UR  - http://dx.doi.org/10.1080/10426507.2023.2175827
UR  - https://doi.org/10.1080/10426507.2023.2175827
UR  - http://hdl.handle.net/10044/1/102649
VL  - 198
ER  -
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