Imperial College London
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DrAndyAshley

Faculty of Natural Sciences, Department of Chemistry

Honorary Lecturer
 
 
 
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Contact

 

+44 (0)20 7594 5810a.ashley Website

 
 
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Location

 

601LMolecular Sciences Research HubWhite City Campus

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Summary

 

Publications

Citation

BibTex format

@article{Ransom:2009:10.1016/j.jorganchem.2008.09.002,
author = {Ransom, P and Ashley, A and Thompson, A and O'Hare, D},
doi = {10.1016/j.jorganchem.2008.09.002},
journal = {J. Organomet. Chem.},
pages = {1059--1068},
title = {Synthesis, structure and characterisation of rac and meso-ansa-bridged permethylindenyl cobalt complexes.},
url = {http://dx.doi.org/10.1016/j.jorganchem.2008.09.002},
volume = {694},
year = {2009}
}
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RIS format (EndNote, RefMan)

TY  - JOUR
AB  - Disodium ethylene-bis-hexamethylindenyl, {(C9Me6)2C2H4}Na2 (EBINa2), has been prepd. in good yield by the reaction of lithium heptamethylindenyl with cyanogen bromide followed by treatment with sodium naphthalenide.  EBINa2 reacts with anhyd. Co(acac)2 to give a mixt. of rac and meso-ethylene-bis-hexamethylindenyl cobalt(II) (EBICo).  The isomers can be sepd. by fractional crystn. and the rac-isomer has been structurally characterized.  Oxidn. of the reaction mixt. yields both rac and meso-ethylene-bis-hexamethylindenyl cobalt(III) which have both been structurally characterized. [on SciFinder(R)]
AU  - Ransom,P
AU  - Ashley,A
AU  - Thompson,A
AU  - O'Hare,D
DO  - 10.1016/j.jorganchem.2008.09.002
EP  - 1068
PY  - 2009///
SN  - 0022-328X
SP  - 1059
TI  - Synthesis, structure and characterisation of rac and meso-ansa-bridged permethylindenyl cobalt complexes.
T2  - J. Organomet. Chem.
UR  - http://dx.doi.org/10.1016/j.jorganchem.2008.09.002
VL  - 694
ER  -
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