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@article{Green:1996:10.1039/CC9960001563,
author = {Green, MJ and Britovsek, GJP and Cavell, KJ and Skelton, BW and White, AH},
doi = {10.1039/CC9960001563},
journal = {Chemical Communications},
pages = {1563--1564},
title = {Ethene insertion into a palladium-acetyl bond: Crystal structure of [Pd(CH2CH2COMe)(NC5H4CO 2Me-2)(PPh3)]BF4, a novel reaction intermediate from the insertion process},
url = {http://dx.doi.org/10.1039/CC9960001563},
year = {1996}
}

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TY  - JOUR
AB  - From the catalytic conversion of CO and ethene to polyketone with [Pd(Me)(NC<inf>5</inf>H<inf>4</inf>CO<inf>2</inf>Me-2)- (PPh<inf>3</inf>)]BF<inf>4</inf> 1, the reaction of ethene with [Pd(COMe)(NC<inf>5</inf>H<inf>4</inf>CO<inf>2</inf>Me-2)-(PPh <inf>3</inf>)]BF<inf>4</inf> 2 yields a rare example of an isolable product from the insertion of an unstrained alkene into a Pd-acyl bond, and the crystal structure of [Pd(CH<inf>2</inf>CH<inf>2</inf>COMe)-(NC<inf>5</inf>H<inf>4</inf>CO <inf>2</inf>Me-2)(PPh<inf>3</inf>)]BF<inf>4</inf> 3 showing a novel square-pyramidal intermediate with a weakly interacting oxygen in the apical position.
AU  - Green,MJ
AU  - Britovsek,GJP
AU  - Cavell,KJ
AU  - Skelton,BW
AU  - White,AH
DO  - 10.1039/CC9960001563
EP  - 1564
PY  - 1996///
SN  - 1359-7345
SP  - 1563
TI  - Ethene insertion into a palladium-acetyl bond: Crystal structure of [Pd(CH2CH2COMe)(NC5H4CO 2Me-2)(PPh3)]BF4, a novel reaction intermediate from the insertion process
T2  - Chemical Communications
UR  - http://dx.doi.org/10.1039/CC9960001563
ER  -

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