In this section
@article{Fainleib:2011,
author = {Fainleib, A and Grigoryeva, O and Youssef, B and Saiter, JM and Bismarck, A},
pages = {321--352},
title = {Modification of polycyanurate network by reactive rubbers with hydrazide, acylhydrazone and isocyanate terminal groups},
year = {2011}
}
TY - JOUR
AB - First, chemical interactions between hydrazide, acylhydrazone and isocyanate groups from one side with cyanate groups from other side have been studied using methods of FTIR spectroscopy and NMR 1H analysis. The formation of the substituted cyanurate (triazine) cycles has been found. These results were confirmed on polymer systems at modification of polycyanurate network (PCN) by reactive rubbers, possessing the above mentioned functional groups, where the chemical reactions found led to incorporation of the rubbers into the PCN network. The partial chemical incorporation of the rubber modifiers' fragments into the PCN network structure has been found. The structure of the final hybrid networks was found to be depended on reactivity of the rubber modifier's functional groups toward cyanate groups and the modifier content in the system. It has been established that the unreacted part of the modifier forms the own separated microphase. The most pronounced two phase structure has been observed for OIDAH rubber with the lowest reactivity towards cyanate groups of the growing PCN network. © 2010 Nova Science Publishers, Inc. All rights reserved.
AU - Fainleib,A
AU - Grigoryeva,O
AU - Youssef,B
AU - Saiter,JM
AU - Bismarck,A
EP - 352
PY - 2011///
SP - 321
TI - Modification of polycyanurate network by reactive rubbers with hydrazide, acylhydrazone and isocyanate terminal groups
ER -
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