BibTex format
@inproceedings{Eckert:2005,
author = {Eckert, CA and Liotta, CL and Bush, D and Hallett, JP and Lazzaroni, MJ},
title = {Vapor-liquid-liquid equilibria of carbon dioxide-organic water systems},
year = {2005}
}
RIS format (EndNote, RefMan)
TY - CPAPER
AB - Homogeneous catalysts offer exciting opportunities for organic synthesis due to high activity and selectivity, but implementation is limited by difficulties in catalyst recycle. The addition of a polar organic co-solvent to a water/organic biphasic system, coupled with subsequent phase splitting induced by the dissolution of gaseous CO<inf>2</inf> creates the opportunity to run homogeneous reactions in an organic/aqueous mixture with a water-soluble catalyst. High-pressure phase equilibria for the systems containing carbon dioxide, an organic solvent (tetrahydrofuran, acetonitrile, or 1,4-dioxane) and water were measured using a variable-volume view cell. These systems are well predicted with the Peng-Robinson Equation of State with Huron-Vidal type mixing rules from correlations of the binary systems. Applications of the phase behavior on reaction conditions and separations will be discussed.
AU - Eckert,CA
AU - Liotta,CL
AU - Bush,D
AU - Hallett,JP
AU - Lazzaroni,MJ
PY - 2005///
TI - Vapor-liquid-liquid equilibria of carbon dioxide-organic water systems
ER -