BibTex format
@article{Kaerger:2025:10.1515/pac-2023-1126,
author = {Kaerger, J and Valiullin, R and Brandani, S and Caro, J and Chmelik, C and Chmelka, BF and Coppens, M-O and Farooq, S and Freude, D and Jobic, H and Kruteva, M and Mangano, E and Pini, R and Price, WS and Rajendran, A and Ravikovitch, PI and Sastre, G and Snurr, RQ and Stepanov, AG and Vasenkov, S and Wang, Y and Weckhuysen, BM},
doi = {10.1515/pac-2023-1126},
journal = {Pure and Applied Chemistry},
pages = {1--89},
title = {Diffusion in nanoporous materials with special consideration of the measurement of determining parameters (IUPAC Technical Report)},
url = {http://dx.doi.org/10.1515/pac-2023-1126},
volume = {97},
year = {2025}
}
RIS format (EndNote, RefMan)
TY - JOUR
AB - The random motion (the diffusion) of guest molecules in nanoporous host materials is key to their manifold technological applications and, simultaneously, a ubiquitous phenomenon in nature quite in general. Based on a specification of the different conditions under which molecular diffusion in nanoporous materials may occur and of the thus resulting relevant parameters, a survey of the various ways of the measurement of the determining parameters is given. Starting with a condensed introduction to the respective measuring principles, the survey notably includes a summary of the various parameters accessible by each individual technique, jointly with an overview of their strengths and weaknesses as well as of the respective ranges of observation. The presentation is complemented by basic relations of diffusion theory and molecular modeling in nanoporous materials, illustrating their significance for enhancing the informative value of each measuring technique and the added value attainable by their combination. By providing guidelines for the measurement and reporting of diffusion properties of chemical compounds in nanopores, the document aims to contribute to the clarification and standardization of the presentation, nomenclature, and methodology associated with the documentation of diffusion phenomena in nanoporous materials serving for catalytic, mass separation, and other relevant purposes.
AU - Kaerger,J
AU - Valiullin,R
AU - Brandani,S
AU - Caro,J
AU - Chmelik,C
AU - Chmelka,BF
AU - Coppens,M-O
AU - Farooq,S
AU - Freude,D
AU - Jobic,H
AU - Kruteva,M
AU - Mangano,E
AU - Pini,R
AU - Price,WS
AU - Rajendran,A
AU - Ravikovitch,PI
AU - Sastre,G
AU - Snurr,RQ
AU - Stepanov,AG
AU - Vasenkov,S
AU - Wang,Y
AU - Weckhuysen,BM
DO - 10.1515/pac-2023-1126
EP - 89
PY - 2025///
SN - 0033-4545
SP - 1
TI - Diffusion in nanoporous materials with special consideration of the measurement of determining parameters (IUPAC Technical Report)
T2 - Pure and Applied Chemistry
UR - http://dx.doi.org/10.1515/pac-2023-1126
UR - https://www.degruyter.com/document/doi/10.1515/pac-2023-1126/html
VL - 97
ER -