In this section
@article{Azzan:2025:10.1007/s10450-025-00599-3,
author = {Azzan, H and Gmyrek, K and Danaci, D and Rajagopalan, AK and Petit, C and Pini, R},
doi = {10.1007/s10450-025-00599-3},
journal = {Adsorption},
title = {Effective macropore diffusivity of carbon dioxide on binderless pellets of Y-type zeolites},
url = {http://dx.doi.org/10.1007/s10450-025-00599-3},
volume = {31},
year = {2025}
}
TY - JOUR
AB - The adsorption kinetics of carbon dioxide (CO2) in three cationic forms of binderless pellets of Y-types zeolites (H-Y, Na-Y, and TMA exchanged Na-Y) are studied using the zero-length column (ZLC) technique. The measurements were carried out at 288.15 K, 298.15 K and 308.15 K using different flowrates and an initial CO2 partial pressure of 0.10 bar – conditions representative of post-combustion CO2 capture applications. The mass transport within the adsorbent pellets was described using a 1-D Fickian diffusion model accounting for intra- and inter-crystalline mass transport. For the latter, the parallel pore model formulation was used to explicitly account for the adsorbent’s macropore size distribution in estimating the volume-averaged diffusivity of the gas. Experiments carried out using different carrier gases, namely helium and nitrogen, were used (i) to determine that these systems are macropore diffusion limited and (ii) to simplify the parameter estimation to a single parameter - the macropore tortuosity. The latter (τ = 1.3 − 2.5) was in good agreement with independent measurements using MIP (τ ≈ 1.7). The associated diffusion coefficient, Demac, was found to vary due to differences in the materials’ macropore size distributions and overall porosity. Upon combining the parallel pore model formulation with the temperature dependencies for the pore diffusivities derived from molecular theories of gases, we predict Demac ∝ Tb with b = [0.78 − 0.88] depending on the macropore size distribution. Notably, for the range of temperature tested in this study, Demac varies approximately linearly with temperature (b ≈ 1)– in contrast to the commonly reported correlation of b = 1.75, which may be more appropriate for systems where molecular diffusion dominates and Knudsen diffusion is negligible. The binderless pellets of Y-type zeolites studied exhibit generally higher values for the effective macropore diffus
AU - Azzan,H
AU - Gmyrek,K
AU - Danaci,D
AU - Rajagopalan,AK
AU - Petit,C
AU - Pini,R
DO - 10.1007/s10450-025-00599-3
PY - 2025///
SN - 0929-5607
TI - Effective macropore diffusivity of carbon dioxide on binderless pellets of Y-type zeolites
T2 - Adsorption
UR - http://dx.doi.org/10.1007/s10450-025-00599-3
UR - https://link.springer.com/article/10.1007/s10450-025-00599-3
VL - 31
ER -