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@article{Petersen:2014:10.1021/ja5055143,
author = {Petersen, AR and Taylor, RA and Vicente-Hernandez, I and Mallender, PR and Olley, H and White, AJP and Britovsek, GJP},
doi = {10.1021/ja5055143},
journal = {Journal of the American Chemical Society},
pages = {14089--14099},
title = {Oxygen insertion into metal carbon bonds: formation of methylperoxo Pd(II) and Pt(II) complexes via photogenerated dinuclear intermediates},
url = {http://dx.doi.org/10.1021/ja5055143},
volume = {136},
year = {2014}
}

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TY  - JOUR
AB  - Platinum(II) and palladium(II) complexes [M(CH)(L)]SbF with substituted terpyridine ligands L undergo light-driven oxygen insertion reactions into metal methyl bonds resulting in methylperoxo complexes [M(OOCH)(L)]SbF. The oxygen insertion reactions occur readily for complexes with methyl ligands that are activated due to steric interaction with substituents (NH, NHMe or CH) at the 6,6″-positions on the terpyridine ligand. All complexes exhibit attractive intermolecular π···π or M···M interactions in the solid state and in solution, which lead to excited triplet dinuclear M–M complexes upon irradiation. A mechanism is proposed whereby a dinuclear intermediate is generated upon irradiation that has a weakened M–C bond in the excited state, resulting in the observed oxygen insertion reactions.
AU  - Petersen,AR
AU  - Taylor,RA
AU  - Vicente-Hernandez,I
AU  - Mallender,PR
AU  - Olley,H
AU  - White,AJP
AU  - Britovsek,GJP
DO  - 10.1021/ja5055143
EP  - 14099
PY  - 2014///
SN  - 1520-5126
SP  - 14089
TI  - Oxygen insertion into metal carbon bonds: formation of methylperoxo Pd(II) and Pt(II) complexes via photogenerated dinuclear intermediates
T2  - Journal of the American Chemical Society
UR  - http://dx.doi.org/10.1021/ja5055143
UR  - https://pubs.acs.org/doi/10.1021/ja5055143
UR  - http://hdl.handle.net/10044/1/27101
VL  - 136
ER  -

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