In this section
@article{Vermesi:2016:10.1016/j.combustflame.2015.08.006,
author = {Vermesi, I and Roenner, N and Pironi, P and Hadden, R and Rein, G},
doi = {10.1016/j.combustflame.2015.08.006},
journal = {Combustion and Flame},
pages = {31--41},
title = {Pyrolysis and ignition of a polymer by transient irradiation},
url = {http://dx.doi.org/10.1016/j.combustflame.2015.08.006},
volume = {163},
year = {2016}
}
TY - JOUR
AB - Pyrolysis is the thermochemical process that leads to the ignition of a solid fuel and a key mechanism in flame spread and fire growth. Because polymer materials are flammable and ubiquitous in the modern environment, the understanding of polymer pyrolysis is thus essential to tackle accidental fires. In this paper, we used transient irradiation as an external source of heat to study the process of pyrolysis and ignition of a polymer sample. While previous ignition studies use constant irradiation, transient irradiation is the most frequent condition found in accidental fires, but it lacks a theoretical framework since it has been largely ignored in the literature. Moreover, transient irradiation is a more comprehensive case for the understanding of pyrolysis where nonlinear heat transfer effects challenge the validity of solid-phase criteria for flaming ignition developed previously. We propose here that transient irradiation is the general problem to solid fuel ignition of which constant irradiation is a particular solution. In order to investigate how this novel heat source inuences polymer pyrolysis and flammability, numerical simulations and experiments have been conducted on Poly(methyl methacrylate) (PMMA) samples 100mm by 100mm and 30mm deep exposed to a range of parabolic pulses of irradiation. The 1D model, coded in GPyro, uses heat and mass transfer and single-step heterogeneous chemistry, with temperature dependent properties. The predictions are compared to experiments conducted in the Fire Propagation Apparatus using both constant and transient irradiation conditions. The experiments validate the temperature predictions of the model and also provide the time to ignition. The model then complements the experiments by calculating the mass loss rate. A series of 16 parabolic pulses (including repeats) are investigated with a range of peak irradiation from 25 to 45 kW/m2, while the time to peak ranges from 280 to 480s. For these pulses, the time to igniti
AU - Vermesi,I
AU - Roenner,N
AU - Pironi,P
AU - Hadden,R
AU - Rein,G
DO - 10.1016/j.combustflame.2015.08.006
EP - 41
PY - 2016///
SN - 0010-2180
SP - 31
TI - Pyrolysis and ignition of a polymer by transient irradiation
T2 - Combustion and Flame
UR - http://dx.doi.org/10.1016/j.combustflame.2015.08.006
UR - https://www.sciencedirect.com/science/article/pii/S0010218015002667
UR - http://hdl.handle.net/10044/1/25644
VL - 163
ER -
Phone:
+44 (0)20 7594 7036
Email:
g.rein@imperial.ac.uk
Address:
Department of Mechanical Engineering,
City & Guilds Building,
South Kensington Campus, London, SW7 2AZ, UK