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• Patent
  kucernak, brandon, yufit, 2013,

  regenerative fuel cells

  The present invention provides a regenerative fuel cell comprising an anionic membrane capable of selectively passing anions, wherein the pH of the anolyte and/or catholyte is at least 10. The present invention also relates to a method of operating a regenerative fuel cell comprising an anionic membrane capable of selectively passing anions, wherein the pH of the anolyte and/or catholyte is at least 10.

  • Abstract
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• Journal article
  Turek VA, Elliott LN, Tyler AII, Demetriadou A, Paget J, Cecchini MP, Kucernak AR, Kornyshev AA, Edel JBet al., 2013,

  Self-Assembly and Applications of Ultra-Concentrated Nanoparticle Solutions

  , ACS Nano
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• Conference paper
  Thepkaew J, Therdthianwong S, Therdthianwong A, Kucernak A, Wongyao Net al., 2013,

  Promotional roles of Ru and Sn in mesoporous PtRu and PtRuSn catalysts toward ethanol electrooxidation

  , 3rd International Conference of Fuel Cell & Hydrogen Technology (ICFCHT), Publisher: PERGAMON-ELSEVIER SCIENCE LTD, Pages: 9454-9463, ISSN: 0360-3199
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  • Citations: 29
• Journal article
  Qian H, Kucernak AR, Greenhalgh ES, Bismarck A, Shaffer MSPet al., 2013,

  Multifunctional Structural Supercapacitor Composites Based on Carbon Aerogel Modified High Performance Carbon Fiber Fabric

  , ACS APPLIED MATERIALS & INTERFACES, Vol: 5, Pages: 6113-6122, ISSN: 1944-8244
  • Author Web Link
  • Open Access Link
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  • Citations: 165
• Journal article
  Cousens NEA, Kucernak AR, 2013,

  Electrochemistry of the ionic liquid vertical bar oil interface: A new water-free interface between two immiscible electrolyte solutions

  , ELECTROCHEMISTRY COMMUNICATIONS, Vol: 31, Pages: 63-66, ISSN: 1388-2481
  • Author Web Link
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  • Citations: 7
• Journal article
  Ahmad EA, Mallia G, Kramer D, Kucernak AR, Harrison NMet al., 2013,

  The stability of LaMnO3 surfaces: a hybrid exchange density functional theory study of an alkaline fuel cell catalyst (vol 1, pg 11152, 2013)

  , JOURNAL OF MATERIALS CHEMISTRY A, Vol: 1, Pages: 15555-15555, ISSN: 2050-7488
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• Conference paper
  Greenhalgh ES, Ankersen J, Asp LE, Bismarck A, Fontana QPV, Houlle M, Kalinka G, Kucernak A, Mistry M, Nguyen S, Qian H, Shaffer MSP, Shirshova N, Steinke JHG, Wienrich Met al., 2013,

  Mechanical and microstructural characterisation of multifunctional structural power composites

  , Pages: 2228-2237
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  • Citations: 1
• Conference paper
  Mistry M, Kucernak A, Nguyen S, Ankersen J, Greenhalgh ESet al., 2013,

  Addressing engineering issues for a composite structural power demonstrator

  , Pages: 2692-2700

  Engineering issues have been addressed for a Multifunctional (MF) Carbon Fibre Reinforced Polymer (CFRP) capable of storing electrical energy and carrying mechanical load. The MF material was integrated into a technology demonstrator in the form of a car boot lid where the boot lighting was powered independently of the car main electrical system. Current collection was improved by using a thin copper mesh on the carbon electrodes while hole drilling was found to have a negligible effect on the laminate electrical performance.

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  • Citations: 3
• Conference paper
  Qian H, Kucernak AR, Greenhalgh ES, Bismarck A, Shaffer MSPet al., 2013,

  Multifunctional structural power composites based on carbon aerogel modified high performance carbon fibre fabrics

  , Pages: 2238-2243
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  • Citations: 6
• Conference paper
  Zalitis CM, Kramer D, Sharman J, Wright E, Kucernak ARet al., 2013,

  Pt Nano-Particle Performance for PEFC Reactions At Low Catalyst Loading and High Reactant Mass Transport

  , 13th Polymer Electrolyte Fuel Cell Symposium (PEFC), Publisher: ELECTROCHEMICAL SOC INC, Pages: 39-47, ISSN: 1938-5862
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  • Citations: 11
• Journal article
  Shirshova N, Bismarck A, Carreyette S, Fontana QPV, Greenhalgh ES, Jacobsson P, Johansson P, Marczewski MJ, Kalinka G, Kucernak ARJ, Scheers J, Shaffer MSP, Steinke JHG, Wienrich Met al., 2013,

  Structural supercapacitor electrolytes based on bicontinuous ionic liquid-epoxy resin systems

  , JOURNAL OF MATERIALS CHEMISTRY A, Vol: 1, Pages: 15300-15309, ISSN: 2050-7488
  • Author Web Link
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  • Citations: 104
• Journal article
  Ahmad EA, Mallia G, Kramer D, Kucernak AR, Harrison NMet al., 2013,

  The stability of LaMnO3 surfaces: a hybrid exchange density functional theory study of an alkaline fuel cell catalyst

  , JOURNAL OF MATERIALS CHEMISTRY A, Vol: 1, Pages: 11152-11162, ISSN: 2050-7488
  • Author Web Link
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  • Citations: 24
• Journal article
  Zalitis CM, Kramer D, Kucernak AR, 2013,

  Electrocatalytic performance of fuel cell reactions at low catalyst loading and high mass transport

  , PHYSICAL CHEMISTRY CHEMICAL PHYSICS, Vol: 15, Pages: 4329-4340, ISSN: 1463-9076
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  • Citations: 134
• Journal article
  Shirshova N, Qian H, Shaffer MSP, Steinke JHG, Greenhalgh ES, Curtis PT, Kucernak A, Bismarck Aet al., 2013,

  Structural composite supercapacitors

  , Composites Part A: Applied Science and Manufacturing, Vol: 46, Pages: 96-107, ISSN: 1359-835X

  This paper presents the development of multifunctional materials that perform a structural role whilst simultaneously storing electrical energy as a supercapacitor. Two structural carbon fibre woven electrodeswere separated by a woven glass fibre layer, and infused with a multifunctional polymer electrolyte. Following characterisation of electrochemical and compressive performance, working structural supercapacitor prototypes were demonstrated. Since the relative mechanical and electrical demands are application specific, an optimisation methodology is proposed. Multifunctional composites were achieved, which had compressive moduli of up to 39 GPa and capacitances of up to 52 mF g 1.

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• Journal article
  Kucernak A, Bidault F, Smith G, 2012,

  Membrane electrode assemblies based on porous silver electrodes for alkaline anion exchange membrane fuel cells

  , ELECTROCHIMICA ACTA, Vol: 82, Pages: 284-290, ISSN: 0013-4686
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  • Citations: 24
• Journal article
  Thepkaew J, Therdthianwong S, Kucernak A, Therdthianwong Aet al., 2012,

  Electrocatalytic activity of mesoporous binary/ternary PtSn-based catalysts for ethanol oxidation

  , JOURNAL OF ELECTROANALYTICAL CHEMISTRY, Vol: 685, Pages: 41-46, ISSN: 1572-6657
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  • Citations: 11
• Journal article
  Jiang J, Kucernak A, 2012,

  Mass transport and kinetics of electrochemical oxygen reduction at nanostructured platinum electrode and solid polymer electrolyte membrane interface

  , JOURNAL OF SOLID STATE ELECTROCHEMISTRY, Vol: 16, Pages: 2571-2579, ISSN: 1432-8488
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  • Citations: 9
• Conference paper
  Bismarck A, Carreyette S, Fontana QPV, Greenhalgh ES, Jacobsson P, Johansson P, Marczewski MJ, Kalinka G, Kucernak A, Shaffer MS, Shirshova N, Steinke JHG, Wienrich Met al., 2012,

  Multifunctional epoxy resin for structural supercapacitors

  , 15th European Conference on Composite Materials, Publisher: European Socirty for Composite Materials, Pages: 1-8

  Polymer-based electrolytes based on commercially available epoxy resins were prepared through the addition of a liquid electrolyte, a solution of a lithium salt in an ionic liquid. The polymer monoliths were characterized using impedance spectroscopy, 3-point bending test, scanning electron microscopy (SEM) and nitrogen adsorption (BET). The balance of ionic conductivity and flexural modulus is crucially dependent on the relative proportions of epoxy resin to electrolyte. Also the effect of the liquid electrolyte on curing kinetics and processing was assessed by complex viscosity measurements and differential scanning calorimetry (DSC). Only one out of the three resins investigated exhibited a significant acceleration effect.

  • Abstract
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• Journal article
  Ahmad EA, Mallia G, Kramer D, Tileli V, Kucernak AR, Harrison NMet al., 2012,

  Comment on "2D Atomic Mapping of Oxidation States in Transition Metal Oxides by Scanning Transmission Electron Microscopy and Electron Energy-Loss Spectroscopy"

  , PHYSICAL REVIEW LETTERS, Vol: 108, ISSN: 0031-9007
  • Author Web Link
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  • Citations: 6
• Journal article
  Turek V, Cecchini MP, Paget J, Kucernak AR, Kornyshev AA, Edel JBet al., 2012,

  A Plasmonic Ruler at the Liquid-Liquid Interface

  , ACS Nano
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• Journal article
  Cousens NEA, Kucernak AR, 2011,

  Increasing the potential window of the interface between two immiscible electrolyte solutions to more than 1.2 V

  , ELECTROCHEMISTRY COMMUNICATIONS, Vol: 13, Pages: 1539-1541, ISSN: 1388-2481
  • Author Web Link
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  • Citations: 17
• Conference paper
  Shirshova N, Shaffer M, Steinke JHG, Greenhalgh E, Curtis P, Bismarck Aet al., 2011,

  Structural Polymer Composites for Energy Storage Devices

  , International Conference on Advanced Capacitors (ICAC2007)
  • Cite
• Journal article
  Ahmad EA, Liborio L, Kramer D, Mallia G, Kucernak AR, Harrison NMet al., 2011,

  Thermodynamic stability of LaMnO3 and its competing oxides: A hybrid density functional study of an alkaline fuel cell catalyst

  , PHYSICAL REVIEW B, Vol: 84, ISSN: 2469-9950
  • Author Web Link
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  • Citations: 34
• Conference paper
  Elias S, Quinson J, Britovsek GJP, Kucernak ARJet al., 2011,

  Electrocatalytic CO2 reduction using modified electrodes

  , 242nd National Meeting of the American-Chemical-Society (ACS), Publisher: AMER CHEMICAL SOC, ISSN: 0065-7727
  • Author Web Link
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• Journal article
  Bidault F, Kucernak A, 2011,

  Cathode development for alkaline fuel cells based on a porous silver membrane

  , JOURNAL OF POWER SOURCES, Vol: 196, Pages: 4950-4956, ISSN: 0378-7753
  • Author Web Link
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  • Citations: 24
• Journal article
  Sleightholme AES, Kucernak A, 2011,

  An anomalous peak observed in the electrochemistry of the platinum/perfluorosulfonic acid membrane interface

  , ELECTROCHIMICA ACTA, Vol: 56, Pages: 4396-4402, ISSN: 0013-4686
  • Author Web Link
  • Open Access Link
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  • Citations: 9
• Conference paper
  Shirshova N, Shaffer M, Steinke JHG, Greenhalgh E, Curtis P, Bismarck Aet al., 2011,

  Strutural Polymer Composites for Energy Storage Devices

  , 1st Chemical and Biomedical Engineering Symposium
  • Cite
• Conference paper
  Mao B, Kurtoglu A, Kucernak ARJ, Shaffer Met al., 2011,

  Exploiting carbon nanotubes in fuel cells

  , NSTI Nanotechnology Conference and Expo, Publisher: CRC PRESS-TAYLOR & FRANCIS GROUP, Pages: 807-809
  • Author Web Link
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• Journal article
  Marinescu M, Urbakh M, Barnea T, Kucernak AR, Kornyshev AAet al., 2010,

  Electrowetting Dynamics Facilitated by Pulsing

  , JOURNAL OF PHYSICAL CHEMISTRY C, Vol: 114, Pages: 22558-22565, ISSN: 1932-7447
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  • Citations: 17
• Conference paper
  Xu H, Zalitis C, Rivera-Hernandez M, Albrecht T, Kucernak Aet al., 2010,

  Fuel cell catalysts based on core-shell nano-particles

  , Pages: 475-476

  In this work, we used platinum black to improve the dispersion mechanisms onto highly oriented pyrolytic graphite substrates by using different solvents in order to develop a methodology to disperse core-shell Pt nanoparticles. With this technique, we found that pure isopropyl alcohol exhibited better dispersion onto graphite in comparison with a mixed solution. Although SEM and STM images revealed in general a poor dispersion, some aggregates and few individual particles scattered onto the graphite surface were observed.

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