@article{Tan:2023:10.1002/advs.202206888,
author = {Tan, R and Wang, A and Ye, C and Li, J and Liu, D and Darwich, BP and Petit, L and Fan, Z and Wong, T and Alvarez-Fernandez, A and Furedi, M and Guldin, S and Breakwell, CE and Klusener, PAA and Kucernak, AR and Jelfs, KE and McKeown, NB and Song, Q},
doi = {10.1002/advs.202206888},
journal = {Advanced Science},
pages = {1--11},
title = {Thin film composite membranes with regulated crossover and water migration for long-life aqueous redox flow batteries.},
url = {http://dx.doi.org/10.1002/advs.202206888},
volume = {10},
year = {2023}
}

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TY  - JOUR
AB  - Redox flow batteries (RFBs) are promising for large-scale long-duration energy storage owing to their inherent safety, decoupled power and energy, high efficiency, and longevity. Membranes constitute an important component that affects mass transport processes in RFBs, including ion transport, redox-species crossover, and the net volumetric transfer of supporting electrolytes. Hydrophilic microporous polymers, such as polymers of intrinsic microporosity (PIM), are demonstrated as next-generation ion-selective membranes in RFBs. However, the crossover of redox species and water migration through membranes are remaining challenges for battery longevity. Here, a facile strategy is reported for regulating mass transport and enhancing battery cycling stability by employing thin film composite (TFC) membranes prepared from a PIM polymer with optimized selective-layer thickness. Integration of these PIM-based TFC membranes with a variety of redox chemistries allows for the screening of suitable RFB systems that display high compatibility between membrane and redox couples, affording long-life operation with minimal capacity fade. Thickness optimization of TFC membranes further improves cycling performance and significantly restricts water transfer in selected RFB systems.
AU  - Tan,R
AU  - Wang,A
AU  - Ye,C
AU  - Li,J
AU  - Liu,D
AU  - Darwich,BP
AU  - Petit,L
AU  - Fan,Z
AU  - Wong,T
AU  - Alvarez-Fernandez,A
AU  - Furedi,M
AU  - Guldin,S
AU  - Breakwell,CE
AU  - Klusener,PAA
AU  - Kucernak,AR
AU  - Jelfs,KE
AU  - McKeown,NB
AU  - Song,Q
DO  - 10.1002/advs.202206888
EP  - 11
PY  - 2023///
SN  - 2198-3844
SP  - 1
TI  - Thin film composite membranes with regulated crossover and water migration for long-life aqueous redox flow batteries.
T2  - Advanced Science
UR  - http://dx.doi.org/10.1002/advs.202206888
UR  - https://www.ncbi.nlm.nih.gov/pubmed/37178400
UR  - https://onlinelibrary.wiley.com/doi/10.1002/advs.202206888
UR  - http://hdl.handle.net/10044/1/104400
VL  - 10
ER  - 

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