In this section
@article{Malko:2017:10.1016/j.elecom.2017.09.004,
author = {Malko, D and Kucernak, ARJ},
doi = {10.1016/j.elecom.2017.09.004},
journal = {Electrochemistry Communications},
pages = {67--71},
title = {Kinetic isotope effect in the oxygen reduction reaction (ORR) over Fe-N/C catalysts under acidic and alkaline conditions.},
url = {http://dx.doi.org/10.1016/j.elecom.2017.09.004},
volume = {83},
year = {2017}
}
TY - JOUR
AB - Heat treated Fe-N/C materials which are highly effective oxygen reduction catalysts in alkaline and acid, show a significant kinetic isotope effect (KIE). The values in acid (~3.4) and alkaline (~2.5) are much larger than the value for the metal free catalyst in acid (~1.8) suggesting that the rate determining step (RDS) is a proton coupled electron transfer in acid with a significant pathway involving a proton independent step under an alkaline environment
AU - Malko,D
AU - Kucernak,ARJ
DO - 10.1016/j.elecom.2017.09.004
EP - 71
PY - 2017///
SN - 1388-2481
SP - 67
TI - Kinetic isotope effect in the oxygen reduction reaction (ORR) over Fe-N/C catalysts under acidic and alkaline conditions.
T2 - Electrochemistry Communications
UR - http://dx.doi.org/10.1016/j.elecom.2017.09.004
UR - http://hdl.handle.net/10044/1/50616
VL - 83
ER -
Prof. Anthony Kucernak
G22B
Molecular Sciences Research Hub (MSRH)
Imperial College London
White City Campus
London
W12 0BZ
United Kingdom
Phone: +44 (0)20 7594 5831
Fax: +44 (0)20 7594 5804
Email: anthony@imperial.ac.uk