In this section
@article{Freeman:2015:10.1039/c5py01473e,
author = {Freeman, DME and Minotto, A and Duffy, W and Fallon, KJ and McCulloch, I and Cacialli, F and Bronstein, H},
doi = {10.1039/c5py01473e},
journal = {Polymer Chemistry},
pages = {722--730},
title = {Highly red-shifted NIR emission from a novel anthracene conjugated polymer backbone containing Pt(II) porphyrins},
url = {http://dx.doi.org/10.1039/c5py01473e},
volume = {7},
year = {2015}
}
TY - JOUR
AB - We present the synthesis of a novel diphenylanthracene (DPA) based semiconducting polymer. The polymer is solubilised by alkoxy groups attached directly to a DPA monomer, meaning the choice of co-monomer is not limited to exclusively highly solubilising moieties. Interestingly, the polymer shows a red-shifted elecroluminescence maximum (510 nm) when compared to its photoluminescence maximum (450 nm) which we attribute to excimer formation. The novel polymer was utilised as a host for a covalently-linked platinum(II) complexed porphyrin dopant. Emission from these polymers was observed in the NIR and again showed almost a 100 nm red shift from photoluminescence to electroluminescence. This work demonstrates that utilising highly aggregating host materials is an effective tool for inducing red-shifted emission in OLEDs.
AU - Freeman,DME
AU - Minotto,A
AU - Duffy,W
AU - Fallon,KJ
AU - McCulloch,I
AU - Cacialli,F
AU - Bronstein,H
DO - 10.1039/c5py01473e
EP - 730
PY - 2015///
SN - 1759-9954
SP - 722
TI - Highly red-shifted NIR emission from a novel anthracene conjugated polymer backbone containing Pt(II) porphyrins
T2 - Polymer Chemistry
UR - http://dx.doi.org/10.1039/c5py01473e
VL - 7
ER -