Polymers and Microfluidics

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We investigate the effect of added (NaCl) salt and varying flow rate on the phase behaviour and flow response of a model surfactant Lα phase, sodium dodecyl sulfate (SDS)/octanol/water, using small angle neutron scattering (SANS) and polarised optical microscopy in microfluidics, supported by NMR, viscosity, conductivity and zeta potential measurements. A long (∼3 m) tubular microchannel device is employed to quantify the spatiotemporal structural evolution of the system towards multilamellar vesicles (MLV). The effect of salt is rationalised in terms of changes in membrane bending rigidity and phase stability. It is shown that ∼1.8 w/w% NaCl addition results in MLV formation within the shortest time (or equivalent lengthscale) and yields near-centrosymmetric scattering profiles characteristic of MLVs (at a reference 1 mL h−1 flow rate and ≃90 s−1 shear rate).

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