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  • Journal article
    Hu S, Reddyhoff T, Puhan D, Vladescu S-C, Shi X, Dini D, Peng Zet al., 2020,

    Droplet manipulation of hierarchical steel surfaces using femtosecond laser fabrication

    , Applied Surface Science, Vol: 521, Pages: 146474-146474, ISSN: 0169-4332
  • Journal article
    Lu J, Reddyhoff T, Dini D, 2020,

    A study of thermal effects in EHL rheology and friction using infrared microscopy

    , Tribology International, Vol: 146, Pages: 106179-106179, ISSN: 0301-679X
  • Journal article
    Heyes DM, Dini D, Smith ER, 2020,

    Single trajectory transport coefficients and the energy landscape by molecular dynamics simulations

    , The Journal of Chemical Physics, Vol: 152, Pages: 194504-194504, ISSN: 0021-9606
  • Journal article
    Fry B, Chui MY, Moody G, Wong Jet al.,

    Interactions between organic friction modifier additives

    , Tribology International, ISSN: 0301-679X

    The interactions of different additives in engine oils can create synergistic or antagonistic effects. This paper studies how mixing different organic friction modifier additives affects friction reducing properties of lubricants in the boundary lubrication regime. Amines of different degree of saturation were mixed with either glycerol monooleate (GMO) or oleic acid in hexadecane. The model lubricants thus formed were characterised with Fourier-transform infrared spectroscopy. Friction tests in reciprocating motion using ball-on-disc steel-steel contacts were conducted to examine the tribological performance of these lubricants. Worn surfaces were examined using X-ray photoelectron spectroscopy. Oleic acid and oleylamine, a primary amine. Were found to form a partial ionic liquid, providing synergistic friction reduction. This positive interaction reduces with increasing degree of saturation of the amine. No synergistic effect was observed between GMO and oleylamine,suggesting that GMO does not hydrolyse into a carboxylic acid within a rubbing contact in the presence of amine. Keywords: Boundary Lubrication, Additives, Friction Abbreviations: organic friction modifier (OFM); glycerol monooleate (GMO); ionic liquid (IL); oleylamine (OA); diocylamine (DA); trihexylamine (TA); dimethylhexadecaylamine (DM16); high frequency reciprocating rig (HFRR); X-ray photoelectron spectroscopy (XPS).

  • Journal article
    Shen L, Denner F, Morgan N, Van Wachem B, Dini Det al.,

    Transient structures in rupturing thin-films: Marangoni-induced symmetry-breaking pattern formation in viscous fluids

    , Science Advances, ISSN: 2375-2548
  • Journal article
    Xu Y, Dini D, 2020,

    Capturing the hardness of coating systems across the scales

    , Surface and Coatings Technology, Pages: 125860-125860, ISSN: 0257-8972

    A two-dimensional multi-scale modelling approach that concurrently couples discrete dislocation plasticity and crystal plasticity finite element has been applied to study the hardness variation of coating systems across different scales, covering nano- to micro-indentation. The difference in indentation size sensitivity between film and substrate gives rise to three regimes of hardness, one typically dictated by the intrinsic coating indentation size effect, which is regulated by dislocations activity, and the other two linked to the continuum response of the coating and the substrate. We propose a new hardness formula that incorporates physics-based indentation size effects of thin films into established continuum hardness transition formulae. This formula is shown to substantially improve the hardness prediction of coating systems, particularly when relative indentation depth is at the nanometre scale.

  • Journal article
    Ajdari N, Tempelaere C, Masouleh MI, Abel R, Delfosse D, Emery R, Dini D, Hansen Uet al., 2020,

    Hemiarthroplasties: the choice of prosthetic material causes different levels of damage in the articular cartilage

    , JOURNAL OF SHOULDER AND ELBOW SURGERY, Vol: 29, Pages: 1019-1029, ISSN: 1058-2746
  • Journal article
    Ewen JP, Ayestarán Latorre C, Gattinoni C, Khajeh A, Moore JD, Remias J, Martini A, Dini Det al., 2020,

    Substituent effects on the thermal decomposition of phosphate esters on ferrous surfaces

    , The Journal of Physical Chemistry C, Vol: 124, Pages: 9852-9865, ISSN: 1932-7447

    Phosphate esters have a wide range of industrial applications, for example in tribology where they are used as vapour phase lubricants and antiwear additives. An atomic-level understanding of phosphate ester tribofilm formation mechanisms is required to improve their tribological performance. A process of particular interest is the thermal decomposition of phosphate esters on steel surfaces, since this initiates polyphosphate film formation. In this study, reactive force field (ReaxFF) molecular dynamics (MD) simulations are used to study the thermal decomposition of phosphate esters with different substituents on several ferrous surfaces. The ReaxFF parameterisation was validated for a representative system using density functional theory (DFT) calculations. During the MD simulations on Fe3O4(001) and α-Fe(110), chemisorption interactions between the phosphate esters and the surfaces occur even at room temperature, and the number of molecule-surface bonds increases as the temperature increases from 300 to 1000 K. Conversely, on hydroxylated, amorphous Fe3O4, most of the molecules are physisorbed and some desorption occurs at high temperature. Thermal decomposition rates were much higher on Fe3O4(001) and particularly α-Fe(110) compared to hydroxylated, amorphous Fe3O4. This suggests that water passivates ferrous surfaces and inhibits phosphate ester chemisorption, decomposition, and ultimately polyphosphate film formation. For the alkyl phosphates, thermal decomposition proceeds mainly through C-O and C-H cleavage on Fe3O4(001). Aryl phosphates show much higher thermal stability, and decomposition on Fe3O4(001) only occurs through P-O and C-H cleavage, which require very high temperature. The onset temperature for C-O cleavage on Fe3O4(001) increases as: tertiary alkyl < secondary alkyl < primary linear alkyl ≈ primary branched alkyl < aryl. This order is consistent with experimental observations for the thermal stability of antiwear addi

  • Journal article
    Smith E, Trevelyan D, Ramos-Fernandez E, Sufian A, O'Sullivan C, Dini Det al., 2020,

    CPL library - a minimal framework for coupled particle and continuum simulation

    , Computer Physics Communications, Vol: 250, Pages: 1-11, ISSN: 0010-4655

    We present an open-source library for coupling particle codes, such as molecular dynamics (MD) or the discrete element method (DEM), and grid based computational fluid dynamics (CFD). The application is focused on domain decomposition coupling, where a particle and continuum software model different parts of a single simulation domain with information exchange. This focus allows a simple library to be developed, with core mapping and communication handled by just four functions. Emphasis is on scaling on supercomputers, a tested cross-language library, deployment with containers and well-documented simple examples. Building on this core, a template is provided to facilitate the user development of common features for coupling, such as averaging routines and functions to apply constraint forces. The interface code for LAMMPS and OpenFOAM is provided to both include molecular detail in a continuum solver and model fluids flowing through a granular system. Two novel development features are highlighted which will be useful in the development of the next generation of multi-scale software: (i) The division of coupled code into a smaller blocks with testing over a range of processor topologies. (ii) The use of coupled mocking to facilitate coverage of various parts of the code and allow rapid prototyping. These two features aim to help users develop coupled models in a test-driven manner and focus on the physics of the problem instead of just software development. All presented code is open-source with detailed documentation on the dedicated website ( permitting useful aspects to be evaluated and adopted in other projects.

  • Journal article
    Gurrutxaga Lerma B, Verschueren J, Sutton A, Dini Det al., 2020,

    The mechanics and physics of high-speed dislocations: a critical review

    , International Materials Reviews, ISSN: 0950-6608

    High speed dislocations have long been identified as the dominant feature governing the plastic response of crystalline materials subjected to high strain rates, controlling deformation and failure in industrial processes such as machining, laser shock peening, punching, drilling, crashworthiness, foreign object damage, etc. Despite decades of study, the role high speed dislocations have on the materials response remains elusive. This article reviews both experimental and theoretical efforts made to address this issue in a systematic way. The lack of experimental evidence and direct observation of high speed dislocations means that most work on the matter is rooted on theory and simulations. This article offers a critical review of the competing theoretical accounts of high speed mechanisms, their underlying hypothesis, insights, and shortcomings, with particular focus on elastic continuum and atomistic levels. The article closes with an overview of the current state of the art and suggestions for key developments in future research.

  • Journal article
    Wen J, Reddyhoff T, Hu S, Puhan D, Dini Det al., 2020,

    Exploiting air cushion effects to optimise a superhydrophobic/hydrophilic patterned liquid ring sealed air bearing

    , Tribology International, Vol: 144, Pages: 106129-106129, ISSN: 0301-679X
  • Journal article
    Menga N, Dini D, Carbone G, 2020,

    Tuning the periodic V-peeling behavior of elastic tapes applied to thin compliant substrates

    , International Journal of Mechanical Sciences, Vol: 170, ISSN: 0020-7403

    In this paper, we investigate the periodic peeling behavior of opposing symmetric peeling fronts involving an elastic tape peeled off from a deformable substrate of finite thickness, backed onto a rigid foundation.We treat the problem by means of an energetic formulation, and we found that, depending on the values of the initial detached length l, substrate thickness h, and peeling periodicity λ, the translational invariance of the peeling process is lost and restored, as the elastic interaction between the peeling fronts is limited by the substrate thickness. Indeed, given h and λ, a critical value of the detached length can be found, which is able to prevent unstable peeling of the tape under a fixed applied load, thus resulting in enhanced adhesion strength, with respect to the classical Kendall’s solution for peeling from a rigid substrate. On the other hand, given the geometrical system configuration (i.e. the detached length l) the load necessary to trigger the peeling can be minimized by conveniently tuning the ratio h/λ. This feature might be of interest for the development of innovative designs for future biomedical devices, such as Transdermal Drug Delivery Systems or wound dressing, requiring low peel adhesion for safe successive removals.

  • Journal article
    Terzano M, Dini D, Rodriguez y Baena F, Spagnoli A, Oldfield Met al., 2020,

    An adaptive finite element model for steerable needles

    , Biomechanics and Modeling in Mechanobiology, ISSN: 1617-7940

    Penetration of a flexible and steerable needle into a soft target material is a complex problem to be modelled, involving several mechanical challenges. In the present paper, an adaptive finite element algorithm is developed to simulate the penetration of a steerable needle in brain-like gelatine material, where the penetration path is not predetermined. The geometry of the needle tip induces asymmetric tractions along the tool–substrate frictional interfaces, generating a bending action on the needle in addition to combined normal and shear loading in the region where fracture takes place during penetration. The fracture process is described by a cohesive zone model, and the direction of crack propagation is determined by the distribution of strain energy density in the tissue surrounding the tip. Simulation results of deep needle penetration for a programmable bevel-tip needle design, where steering can be controlled by changing the offset between interlocked needle segments, are mainly discussed in terms of penetration force versus displacement along with a detailed description of the needle tip trajectories. It is shown that such results are strongly dependent on the relative stiffness of needle and tissue and on the tip offset. The simulated relationship between programmable bevel offset and needle curvature is found to be approximately linear, confirming empirical results derived experimentally in a previous work. The proposed model enables a detailed analysis of the tool–tissue interactions during needle penetration, providing a reliable means to optimise the design of surgical catheters and aid pre-operative planning.

  • Journal article
    Poole B, Barzdajn B, Dini D, Stewart D, Dunne FPEet al., 2020,

    The roles of adhesion, internal heat generation and elevated temperatures in normally loaded, sliding rough surfaces

    , International Journal of Solids and Structures, Vol: 185-186, Pages: 14-28, ISSN: 0020-7683

    The thermal effects of plastic and frictional heat generation and elevated temperature were examined along with the role of adhesion in the context of galling wear, using a representative crystal plasticity, normally loaded, sliding surface model. Galling frequency behaviour was predicted for 316L steel. Deformation of the surfaces was dominated by the surface geometry, with no significant effect due to variations in frictional models. Plastic and frictional heating were found to have a minimal effect on the deformation of the surface, with the rapid conduction of heat preventing any highly localised heating. There was no corresponding effect on the predicted galling frequency response.Isothermal, elevated temperature conditions caused a decrease in galling resistance, driven by the temperature sensitivity of the critical resolved shear stress. The extent of deformation, as quantified by the area of plastically deformed material and plastic reach, increased with temperature. Comparisons were made with literature results for several surface amplitude and wavelength conditions. Model results compared favourably with those in the literature. However, the reduction in predicted galling resistance with elevated temperature for a fixed surface was not as severe as observations in the literature, suggesting other mechanisms (e.g. phase transformations, surface coatings and oxides) are likely important.

  • Journal article
    Zhang J, Spikes H, 2020,

    Measurement of EHD friction at very high contact pressures

    , Tribology Letters, Vol: 68, Pages: 1-12, ISSN: 1023-8883

    EHD friction curves have been measured up to very high pressure (pmean = 5 GPa, pmax = 7.5 GPa) using a newly developed, rolling-sliding, ball on disc machine, the ETM. Six base fluids have been studied, spanning the API base oil categories Group I to Group V. At high pressures, thermal effects become substantial even at quite modest slide-roll ratios, and these must be considered when analysing friction measurements in terms of the underlying rheological properties of the oils. By comparing measurements from steel/steel and WC/WC ball and disc combinations with very different thermal conductivities, the use of thermal correction to derive isothermal friction curves has been validated. At relatively low pressures (mean pressure = 1 GPa), there are substantial differences between the EHD friction properties of the various API Group base oils, but as pressure is raised these diminish and the EHD friction coefficients of all the Groups approach a similar maximum value at a given temperature. EHD friction continues to be quite strongly temperature dependent even at very high pressure. As pressure is increased, EHD friction curves become progressively steeper, so that friction coefficients at very low slide-roll ratios (1 to 2% SRR) become several times greater at high than at low pressure. This has important practical implications for the efficiency of rolling element bearings at high pressures since these components normally operate in this SRR range. There is no evidence of any of the base oils reaching a limiting shear stress over the whole pressure and temperature range studied. Instead, shear stress continues to increase with log(strain rate) in accord with the Eyring-activated flow model up to very high pressures.

  • Journal article
    Kim HM, Spikes H, 2020,

    Correlation of elastohydrodynamic friction with molecular structure of highly refined hydrocarbon base oils

    , Tribology Letters, Vol: 68, Pages: 1-14, ISSN: 1023-8883

    The molecular compositions of a range of low viscosity hydrocarbon base oils spanning API Groups II to IV have been quantified using 13C NMR and correlated with base oil elastohydrodynamic (EHD) friction. A strong correlation has been found between the proportions of paraffin, linear and branched carbons and EHD friction, with a high proportion of linear and paraffinic carbon atoms contributing to low-EHD friction but branched carbons contributing to high-EHD friction. Correlation equations have been developed to predict EHD friction based on base oil composition. At very high temperature and low pressure, this correlation breaks down as the lubricant in the contact does not reach sufficiently high shear stress for shear thinning to occur. For Group IV polyalphaolefin, the correlation must be extended to account for the very high proportion of linear carbons originating from linear alkene oligomerization. The correlations developed in this study can be used to guide the design of low-EHD friction base oils.

  • Journal article
    Fry B, Moody G, Spikes HA, Wong JSSet al., 2020,

    Adsorption of organic friction modifier additives

    , Langmuir, Vol: 36, Pages: 1147-1155, ISSN: 0743-7463

    Organic friction modifier additives (OFMs) are surfactant molecules added to engine oils to reduce friction in the boundary lubrication regime. They are thought to work by forming an absorbed layer which provides low friction. This paper studied the relationship between the adsorption of OFMs and their friction and wear reducing properties in a rubbing contact formed by a stationary glass ball and a rotating silicon disk under the boundary lubrication regime. The effect of molecular structure was investigated by using OFMs of various tail saturation and head group chemistry. OFM tested were oleic acid, octadecylamine, oleylamine and glycerol monooleate. The thickness of an OFM adsorbed layer in hexadecane, examined in-situ by spectroscopic ellipsometry and quartz crystal microbalance (QCM), depends on the molecular structure and the concentration of the OFM. As expected, saturated, linear chain gives the thickest film. A critical OFM layer thickness of about 0.6 nm is necessary to achieve low initial and maximum friction. The thicker OFM layers are accompanied by narrower wear tracks, which are rougher than the wider, smoother wear tracks formed with thinner OFM layers. The interplay between the thickness of the OFM layer and wear track surface roughness results in all OFM layers having similar steady friction. This shows that the apparent effect of OFM depends on the stage of rubbing test: initially on friction; and then subsequently on surface damage. Despite OFMs and the base oil having similar refractive indices, ellipsometry was found to be a suitable technique for examining the adsorption of OFM additives from an oil based solution, and showed reasonable correlation with QCM results.

  • Journal article
    Zhang J, Ewen JP, Ueda M, Wong JSS, Spikes HAet al., 2020,

    Mechanochemistry of zinc dialkyldithiophosphate on steel surfaces under elastohydrodynamic lubrication conditions

    , ACS Applied Materials & Interfaces, Vol: 12, Pages: 6662-6676, ISSN: 1944-8244

    Zinc dialkyldithiophosphate (ZDDP) is added to engine lubricants to reduce wear and ensure reliable operation. ZDDP reacts under rubbing conditions to form protective zinc/iron phosphate tribofilms on steel surfaces. Recently, it has been demonstrated that this process can be promoted by applied stresses in lubricated contacts, as well as temperature, and is thus mechanochemical in origin. In this study, a tribology test rig capable of applying very high loads has been developed to generate ZDDP tribofilms under full-film elastohydrodynamic lubrication (EHL) conditions in steel/steel ball-on-disk contacts. This provides a well-defined temperature and stress environment with negligible direct asperity contact in which to study mechanochemical processes. ZDDPs with branched primary and secondary alkyl substituents have been studied in three base oils, two with high EHL friction and one with low EHL friction. In the high EHL friction base oils, the tribofilm growth rate increases exponentially with shear stress and temperature for both ZDDPs, as predicted by a stress augmented thermal activation model. Conversely, under otherwise identical conditions, negligible ZDDP tribofilm formation takes place in the low EHL friction base oil. This confirms that the ZDDP reaction is driven by macroscopic shear stress rather than hydrostatic pressure. The secondary ZDDP forms tribofilms considerably faster than the primary ZDDP under equivalent conditions, suggesting that the initial decomposition reaction is the rate determining step for tribofilm formation. The rate of tribofilm growth is independent of ZDDP concentration over the range studied, indicating that this process follows zero-order kinetics. Under full-film EHL conditions, ZDDP tribofilm formation is promoted by macroscopic shear stress applied through the base oil molecules, which induces asymmetric stress on adsorbed ZDDP molecules to promote their decomposition and initiate rapid phosphate polymerisation.

  • Book chapter
    Putignano C, Dini D, 2020,

    Contact Mechanics of Rubber and Soft Matter

    , Modeling and Simulation of Tribological Problems in Technology, Editors: Paggi, Hills, Publisher: Springer Nature, ISBN: 978-3-030-20376-4
  • Book chapter
    Ewen J, Ramos Fernandez E, Smith E, Dini Det al., 2020,

    Nonequilibrium Molecular Dynamics Simulations of Tribological Systems

    , Modeling and Simulation of Tribological Problems in Technology, Editors: Paggi, Hills, Publisher: Springer Nature, Pages: 95-130, ISBN: 978-3-030-20376-4
  • Journal article
    Knight C, O'Sullivan C, Dini D, Van Wachem Bet al., 2020,

    Computing drag and interactions between fluid and polydisperse particles in saturated granular materials

    , Computers and Geotechnics, Vol: 117, Pages: 1-16, ISSN: 0266-352X

    Fundamental numerical studies of seepage induced geotechnical instabilities and filtration processes depends on accurate prediction of the forces imparted on the soil grains by the permeating fluid. Hitherto coupled Discrete Element Method (DEM) simulations documented in geomechanics have most often simulated the fluid flow using computational fluid dynamics (CFD) models employing fluid cells that contain a number of particles. Empirical drag models are used to predict the fluid-particle interaction forces using the flow Reynolds number and fluid cell porosity. Experimental verification of the forces predicted by these models at the particle-scale is non-trivial. This contribution uses a high resolution immersed boundary method to model the fluid flow within individual voids in polydisperse samples of spheres to accurately determine the fluid-particle interaction forces. The existing drag models are shown to poorly capture the forces on individual particles in the samples for flow with low Reynolds number values. An alternative approach is proposed in which a radical Voronoi tesselation is applied to estimate a local solids volume fraction for each particle; this local solids fraction can be adopted in combination with existing expressions to estimate the drag force. This tessellation-based approach gives a more accurate prediction of the fluid particle interaction forces.

  • Journal article
    Campen S, Moorhouse SJ, Wong JSS, 2020,

    Mechanism of an asphaltene inhibitor in different depositing environments: Influence of colloid stability

    , Journal of Petroleum Science and Engineering, Vol: 184, ISSN: 0920-4105

    Additives are used to reduce unwanted carbonaceous deposits of asphaltenes on surfaces during petroleum production from natural oil and gas reservoirs. The working mechanism of formulated additive packages can be multifaceted. Additives may be effective in the bulk fluid by preventing asphaltenes aggregation, as well as at the surface by preventing asphaltenes adhesion. In this paper, we investigate the numerous different mechanisms by which an asphaltene inhibitor can interfere with the formation of carbonaceous deposits using a combination of techniques including dynamic light scattering to determine particle size distribution, quartz crystal microbalance with dissipation monitoring to examine deposition behaviour and atomic force microscopy to probe deposit morphology. The tested inhibitor prevents deposition of asphaltenes in toluene, where asphaltenes exist as a stable colloidal dispersion of nanoaggregates, by forming barrier-type films that inhibit asphaltenes adhesion and displacing adsorbed thin films of asphaltenes. However, inhibitor performance in heptane-toluene, where asphaltenes are destabilised, depends on the degree of destabilisation. At low heptane volume fraction, inhibitor slows the rate of deposition and deposition rate decreases with increasing inhibitor concentration. However, at high heptane volume fraction, inhibitor can increase the deposition rate, particularly when used in high concentration. At high heptane volume fraction, inhibitor addition alters the morphology of the deposit from that consisting of large flocculent aggregates to that consisting of smaller, submicrometer aggregates. This is consistent with the finding that inhibitor acts as an anti-agglomerant and prevents the formation of large aggregates in the bulk liquid. This paper shows that the impact of inhibitor addition depends on the environmental conditions encountered and the degree of destabilisation of the asphaltenes. Where inhibitor addition alters the nature of depo

  • Journal article
    Hu S, Cao X, Reddyhoff T, Puhan D, Vladescu S-C, Wang Q, Shi X, Peng Z, deMello AJ, Dini Det al., 2019,

    Self-compensating liquid repellent surfaces with stratified morphology

    , ACS Applied Materials and Interfaces, Vol: 12, Pages: 4174-4182, ISSN: 1944-8244

    Artificial liquid repellent surfaces have recently attracted vast scientific attention; however, achieving mechanical robustness remains a formidable challenge before industrialization can be realized. To this end, inspired by plateaus in geological landscapes, a self-compensating strategy is developed to pave the way for the synthesis of durable repellent surfaces. This self-compensating surface comprises tall hydrophobic structural elements, which can repel liquid droplets. When these elements are damaged, they expose shorter structural elements that also suspend the droplets and thus preserve interfacial repellency. An example of this plateau-inspired stratified surface was created by 3D direct laser lithography micro-nano fabrication. Even after being subjected to serious frictional damage, it maintained static repellency to water with a contact angle above 147 and was simultaneously able to endure high pressures arising from droplet impacts. Extending the scope of nature-inspired functional surfaces from conventional biomimetics to geological landscapes, this works demonstrates that the plateau-inspired self-compensating strategy can provide an unprecedented level of robustness in terms of sustained liquid repellency.

  • Journal article
    Fry B, Moody G, Spikes H, Wong Jet al., 2019,

    Effect of surface cleaning on performance of organic friction modifiers

    , Tribology Transactions, Vol: 63, Pages: 305-313, ISSN: 1040-2004

    The performance of surface active additives, such as friction modifiers, depends on their interactions with surfaces. Their effectiveness thus hinges upon the surface conditions. In this work, the effect of cleaning methods of test substrates on the friction reduction capabilities of different organic friction modifier (OFM) additives was investigated. 52100 steel discs and balls were the test specimens. They were cleaned in five different ways. The cleaned surfaces were characterised by using ellipsometry and atomic force microscopy. The tribological performance of stearic acid (STA), octadecylamine (ODA) and octadecanol (ODO) on these surfaces were then tested. As-received steel surfaces were covered with contaminants which may impede the formation of OFM surface layer. Cleaning these surfaces with solvents cannot completely removed these contaminants, with residue layers remain. Cleaning with oxygen or argon plasma results in cleaner surfaces as compared to those cleaned by solvents only. The impact of the choice of cleaning methods on friction depends on the strength of the interaction between the OFM and the steel surface, which determines the ability of an OFM to displace surface contaminations. Cleaner surfaces result in lower initial friction for STA and ODA. Steady state friction is also affected, but to a smaller extent. It may be because most containments remained in the wear track are mechanically removed during rubbing.

  • Journal article
    Ciniero A, Fatti G, Righi MC, Dini D, Reddyhoff Tet al., 2019,

    A combined experimental and theoretical study on the mechanisms behind tribocharging phenomenon and the influence of triboemission

    , Tribology Online, Vol: 14, Pages: 367-374, ISSN: 1881-218X

    This work describes recent research into the mechanisms behind tribocharging and the influence of triboemission. The term tribocharging is a type of contact-induced electrification and refers to the transfer of charge between rubbing components. The term triboemission, on the other hand, refers to emission of electrons, ions and photons generated when surfaces are rubbed together. The understanding of tribocharging is of wide interest for several industrial applications and in particular the combination of tribocharging and triboemission may be important in lubricated contacts in the formation of boundary lubricant films. We report the use of a unique vacuum measurement system that enables to measure surface charge variations while simultaneously recording triboemission events during the sliding of a diamond tip on silica specimens. Results show for the first time that tribocharging and triboemission behavior are linked and depend on the surface wear. The contribution of contact-induced electrification to the charging of the surface is then described by means of density functional theory (DFT). Results give insight into the transfer of charge from the SiO2 amorphous surface (silica) to the C(111) surface (diamond ) and into the variation of charging during simulated sliding contact.

  • Journal article
    Rogers S, Bowden D, Unnikrishnan R, Scenini F, Preuss M, Stewart D, Dini D, Dye Det al., 2019,

    The interaction of galling and oxidation in 316L stainless steel

    , Wear, ISSN: 0043-1648

    The galling behaviour of 316L stainless steel was investigated in both theunoxidised and oxidised states, after exposure in simulated PWR water for 850hours. Galling testing was performed according to ASTM G196 in ambientconditions. 316L was found to gall by the wedge growth and flow mechanism inboth conditions. This resulted in folds ahead of the prow and adhesivejunction, forming a heavily sheared multilayered prow. The galling trough wasseen to have failed through successive shear failure during wedge flow.Immediately beneath the surface a highly sheared nanocrystalline layer wasseen, termed the tribologically affected zone (TAZ). It was observed thatstrain-induced martensite formed within the TAZ. Galling damage was quantifiedusing Rt (maximum height - maximum depth) and galling area (the proportion ofthe sample which is considered galled), and it was shown that both damagemeasures decreased significantly on the oxidised samples. At an applied normalstress of 4.2 MPa the galled area was 14 % vs. 1.2 % and the Rt was 780 um vs.26 um for the unoxidised and oxidised sample respectively. This trend waspresent at higher applied normal stresses, although less prominent. Thisdifference in galling behaviour is likely to be a result of a reduction inadhesion in the case of the oxidised surface.

  • Journal article
    Ueda M, Kadiric A, Spikes H, 2019,

    On the crystallinity and durability of ZDDP tribofilm

    , Tribology Letters, Vol: 67, Pages: 1-13, ISSN: 1023-8883

    The current trend for using lower-viscosity lubricants with the aim of improving fuel economy of mechanical systems means that machine components are required to operate for longer periods in thin oil film, mixed lubrication conditions, where the risk of surface damage is increased. Consequently, the performance and durability of the tribofilms formed by antiwear additives, and in particular zinc dialkyldithiophosphate (ZDDP), the main antiwear oil additive used in engine oils, has become an increasingly important issue. In this paper, it is confirmed that ZDDP tribofilms are initially relatively easily removed by rubbing but that they become more durable during prolonged rubbing. FIB-TEM analyses at different stages of tribofilm formation show that during the early stages of rubbing only the tribofilm close to the steel substrate is nanocrystalline, while the outer region is amorphous and easily removed. However, after prolonged rubbing all regions of the tribofilm become nanocrystalline and able to withstand rubbing in base oil without being removed. XPS analysis shows that after extended rubbing the outermost polyphosphate structures change from longer-chain structures such as metaphosphate and polyphosphate to shorter-chain structures including orthophosphate. This depolymerization of ZDDP tribofilm from long- to short-chain phosphate and consequent nanocrystallization are driven by heat and shear stress. EDX analysis shows that this conversion is promoted by diffusion of Fe cation into the bulk of the tribofilm. The finding that ZDDP tribofilms evolve during rubbing from a weaker amorphous structure to a more durable nanocrystalline one has important implications in terms of the behaviour of ZDDPs at low concentrations, on non-metallic surfaces and at very high contact pressures, as well as for the development of ZDDP tribofilm, friction and wear models.

  • Journal article
    Profito FJ, Zachariadis DC, Dini D, 2019,

    Partitioned fluid-structure interaction techniques applied to the mixed-elastohydrodynamic solution of dynamically loaded connecting-rod big-end bearings

    , Tribology International, Vol: 140, ISSN: 0301-679X

    The present contribution proposes different partitioned techniques, which are commonly used in fluid-structure interaction (FSI) applications, in the context of tribological simulations of the transient mixed-elastohydrodynamic problem of dynamically loaded connecting-rod bearings. With the premise that the FSI framework developed is general, in the current work the fluid flow effects have been considered through the averaged Reynolds equation by Patir & Cheng and the mass-conserving Elrod-Adams cavitation model. The multiphysics simulation framework developed has been used to simulate the connecting-rod big-end bearings of both heavy-duty diesel and high-speed motorcycle engines. In the latter case, the influence of polymer concentration in VM-containing oils with similar HTHS150 values on the bearing power loss is investigated and discussed in details.

  • Journal article
    Menga N, Carbone G, Dini D, 2019,

    Corrigendum to “Do uniform tangential interfacial stresses enhance adhesion?” [Journal of the Mechanics and Physics of Solids 112 (2018) 145–156]

    , Journal of the Mechanics and Physics of Solids, Vol: 133, Pages: 103744-103744, ISSN: 0022-5096
  • Journal article
    Dawczyk J, Russo J, Spikes H, 2019,

    Ethoxylated amine friction modifiers and ZDDP

    , Tribology Letters, Vol: 67, ISSN: 1023-8883

    The influence of a series of Ethomeens (ethoxylated alkylamine organic friction modifiers) on the durability and friction of tribofilms formed by a commercial blend of primary and secondary ZDDP in sliding/rolling contact has been studied. When pre-formed ZDDP tribofilms are rubbed in Ethomeen solution, boundary friction is reduced and some of the ZDDP film is removed. Ethomeens having just two ethoxy groups give lower boundary friction on ZDDP than those with 15 ethoxy groups, but result in much greater removal of the tribofilm itself. Based on XANES analysis, the film removed by both types of Ethomeen consists primarily of nanocrystalline orthophosphate. The level of boundary friction and its dependence on sliding speed, coupled with the dimensions of the molecules, suggests that the Ethomeens with two ethoxy groups may form quite closely packed vertical monolayers on ZDDP tribofilm surfaces, but that those with fifteen ethoxy groups cannot be close packed; yet they still reduce boundary friction significantly. The study shows that selection of an appropriate aminic friction modifier for use with ZDDP is a balance between its ability to reduce friction and its potentially harmful effect on a ZDDP tribofilm.

  • Journal article
    Heyes DM, Dini D, Costigliola L, Dyre JCet al., 2019,

    Transport coefficients of the Lennard-Jones fluid close to the freezing line.

    , J Chem Phys, Vol: 151, Pages: 204502-204502

    Molecular dynamics simulations have been carried out along four Lennard-Jones (LJ) fluid isomorphs close to the freezing line, covering a temperature, T, in the range of 0.8-350 and a number density, ρ, in the range of 1.1-3.0 in LJ units. Analysis of the transport coefficients is via the Green-Kubo time correlation function method. The radial distribution function, percolation threshold connectivity distance, self-diffusion coefficient, and shear viscosity are shown to be invariant along an isomorph to a very good approximation when scaled with Rosenfeld's macroscopic units, although there are some small departures for T ≃ 1 and lower temperatures. The thermal conductivity is shown for the first time also to be isomorph invariant. In contrast, the Einstein and moment-based frequencies, and especially the bulk viscosity, ηb, show poor isomorphic collapse at low T but not surprisingly tend to an "inverse power" potential limiting value in the high T limit. In the case of the bulk viscosity, the significant departures from invariance arise from oscillations in the pressure autocorrelation function at intermediate times, which scale for inverse power potential systems but not for the LJ case, at least in part, as the pressure and bulk elastic moduli are not isomorph invariant.

  • Journal article
    Costa H, Spikes H, 2019,

    Interactions of ethanol with friction modifiers in model engine lubricants

    , Lubricants, Vol: 7, ISSN: 2075-4442

    When employed as an engine fuel, ethanol can accumulate in the lubricant during use. Previous work has shown that ethanol contamination affects friction and elastohydrodynamic lubrication (EHL) film formation, and also the growth and stability of anti-wear tribofilms. The present work uses spacer-layer ultrathin interferometry and MTM tests to investigate how ethanol (both hydrated and anhydrous) interacts with friction modifiers in model lubricants. Small proportions (5 wt %) of ethanol were added to solutions of friction modifiers (one MoDTC and three organic friction modifiers) in a Group I base oil. For the three organic friction modifiers, the presence of ethanol promoted the formation of thick viscous boundary films so that very low friction coefficients were measured at low entrainment speeds. For the MoDTC additive, the presence of ethanol prevented the formation of a low friction film at low speeds at 70 °C, but this effect disappeared at 100 °C, probably due to ethanol evaporation.

  • Journal article
    Gouda K, Rycerz P, Kadiric A, Morales-Espejel Get al., 2019,

    Assessing the effectiveness of data-driven time-domain condition indicators in predicting the progression of surface distress under rolling contact

    , Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology, Vol: 233, Pages: 1523-1540, ISSN: 1350-6501

    Condition monitoring of machine health via analysis of vibration, acoustic and other signals offers an important tool for reducing the machine downtime and maintenance costs. The key aspect in this process is the ability to relate features derived from the recorded sensor signals to the physical condition of the monitored asset in real time. This paper uses simple machine learning techniques to examine the ability of specific time-domain features obtained from vibration signals to predict the progression of surface distress in lubricated, rolling-sliding contacts, such as those found in rolling bearings and gears. Controlled experiments were performed on a triple-disc rolling contact fatigue rig using seeded-fault roller specimens where micropitting damage was generated and its progression directly observed over millions of contact cycles. Vibration signals were recorded throughout the experiments. Features known as condition indicators were then extracted from the recorded time-domain signals and their evolution related to the observed physical state of the associated specimens using simple machine learning techniques. Five time-domain condition indicators were examined, peak-to-peak, root-mean-square, kurtosis, crest factor and skewness, three of which were found not to be redundant. First, a classification model using KNN nearest neighbor was built with the three informative condition indicators as training data. The cross-validation results indicated that this classifier was able to predict the presence of micropitting damage with a relatively high precision and a low rate of false positives. Secondly, a k-means clustering analysis was performed to measure the significance of each condition indicator by leveraging patterns. The peak-to-peak condition indicator was found to be a good predictor for progression of micropitting damage. In addition, this indicator was able to distinguish between micropitting and pitting failure modes with a high success rate. Finally

  • Journal article
    Ueda M, Spikes H, Kadiric A, 2019,

    In-situ observations of the effect of the ZDDP tribofilm growth on micropitting

    , Tribology International, Vol: 138, Pages: 342-352, ISSN: 0301-679X

    The ongoing trend for using ever lower viscosities of lubricating oils, with the aim of improving the efficiency of mechanical systems, means that machine components are required to operate for longer periods under thin film, mixed lubrication conditions where the risk of surface damage is increased. For this reason, the role of zinc dialkyldithiophosphate (ZDDP) antiwear lubricant additive has become increasingly important in order to provide adequate surface protection. It is known that due to its exceptional effectiveness in reducing surface wear, ZDDP may promote micropitting by preventing adequate running-in of the contacting surfaces. However, the relationship between ZDDP tribofilm growth rate and the evolution of micropitting has not been directly demonstrated. To address this, we report the development of a novel technique using MTM-SLIM to obtain micropitting and observe ZDDP tribofilm growth in parallel throughout a test. This is then applied to investigate the effect of ZDDP concentration and type on micropitting.It is found that oils with higher ZDDP concentrations produce more micropitting but less surface wear and that, at a given concentration, a mixed primary-secondary ZDDP results in more severe micropitting than a primary ZDDP. Too rapid formation of a thick antiwear tribofilm early in the test serves to prevent adequate running-in of sliding parts, which subsequently leads to higher asperity stresses and more asperity stress cycles and consequently more micropitting. Therefore, any adverse effects of ZDDP on micropitting and surface fatigue in general are mechanical in nature and can be accounted for through ZDDP's influence on running-in and resulting asperity stress history. The observed correlation between antiwear film formation rate and micropitting should help in the design of oil formulations that extend component lifetime by controlling both wear and micropitting damage.

  • Journal article
    Xu Y, Balint D, Dini D, 2019,

    A new hardness formula incorporating the effect of source density on indentation response: a discrete dislocation plasticity analysis

    , Surface and Coatings Technology, Vol: 374, Pages: 763-773, ISSN: 0257-8972

    Planar discrete dislocation plasticity (DDP) calculations that simulate thin single crystal films bonded to a rigid substrate indented by a rigid wedge are performed for different values of film thickness and dislocation source density. As in prior studies, an indentation size effect (ISE) is observed when indentation depth is sufficiently small relative to the film thickness. Thedependence of the ISE on dislocation source density is quantified in this study, and a modified form of the scaling law for the dependence of hardness on indentation depth, first derived by Nix and Gao, is proposed, which is valid over the entire range of indentation depths and correlates the length scale parameter with the average dislocation source spacing. Nanoindentation experimental data from the literature are fitted using this formula, which further verifies the proposed scaling of indentation pressure on dislocation source density.

  • Journal article
    Campen SM, Moorhouse SJ, Wong JSS, 2019,

    Effect of aging on the removal of asphaltene deposits with aromatic solvent

    , Langmuir, Vol: 35, Pages: 11995-12008, ISSN: 0743-7463

    Surface-deposition of destabilised colloidal particles of asphaltenes poses a serious and costly problem during petroleum production. Remediation of asphaltene-fouled well-bore and surface facilities is often undertaken by flowing aromatic solvent to remove deposited films. However, little is known about the properties of deposited asphaltene films during their removal by solvent-rinsing. Here, we carry out quartz crystal microbalance with dissipation monitoring (QCM-D) experiments to investigate surface-deposition of destabilized colloidal particles of asphaltenes and their subsequent removal by solvent-rinsing. It is shown that the properties of deposited films during solvent removal depend on the history of the deposit. Newly formed deposit films are removed immediately without significant change in their mechanical properties during removal. However, deposits that remain on the surface for an extended time in a poor solvent (a low-asphaltene solubility solvent), “aged deposits”, are more difficult to remove and exhibit increased dissipation during the removal period, indicating that they swell and are softer. Liquid-cell atomic force microscopy (AFM) confirms that aged deposits swell when the quality of the solvent is subsequently improved by exchanging for a high-asphaltene solubility solvent. Deposit swelling is accompanied by a change in film morphology, from particulate to continuous. Stubborn deposits of aged asphaltene films, which remain after solvent-rinsing, may be partly removed by flowing dissolved asphaltenes in good solvent. Hence, reinjection of asphaltenes during remediation can aid deposit removal.

  • Journal article
    Biancofiore L, Giacopini M, Dini D, 2019,

    Interplay between wall slip and cavitation: A complementary variable approach

    , Tribology International, Vol: 137, Pages: 324-339, ISSN: 0301-679X

    In this work a stable and reliable numerical model based on complementary variables is developed to study lubricated contacts characterised by slip at one or both surfaces and in the presence of cavitation. This model can be used to predict surface behaviour when cavitation induced by e.g. the presence of surface texture, slip, or a combination of the two is encountered, with varying surface parameters. For this purpose, two different algorithms are coupled to predict the formation of cavitation, through a mass-conserving formulation, and the presence of slip at the wall. The possible slippage is described by a limiting shear criterion formulated using a Tresca model. To show the flexibility of our model, several bearing geometries have been analysed, such as a twin parabolic slider, a cosine profile used to mimic a bearing, and a pocketed slider bearing employed to study the effect of surface texture. We observe that the lubrication performance (i.e. low friction coefficient) can be improved by using materials that promote slippage at the moving wall. The location of the slippage region can be optimised to find the lowest value of friction coefficient. Our theoretical developments and numerical implementation are shown to produce useful guidelines to improve and optimise the design of textured superoleophobic surfaces in the presence of lubricated contacts.

  • Journal article
    Guegan J, Southby M, Spikes H, 2019,

    Friction modifier additives, synergies and antagonisms

    , Tribology Letters, Vol: 67, ISSN: 1023-8883

    There is growing interest in reducing friction in lubricated machine components to thereby increase the energy efficiency of machines. One important way to minimise friction is to employ friction modifier additives to reduce friction in thin film boundary lubrication conditions. There are currently three main types of friction modifier additive, organic friction modifiers, oil soluble organomolybdenum friction modifiers and functionalised polymers. In common practice, a single such additive is generally employed in a formulated lubricant, but it is of interest to explore whether combinations of two friction modifier additives may prove beneficial. In this study, the performance of eight commercial friction modifier additives spanning all three main types was first measured in three quite different friction tests. The aim was to identify the contact conditions under which each additive was most effective. Additive solutions in both a base oil and a formulated engine oil were investigated. In general, functionalised polymers were most beneficial in sliding–rolling contacts, while oil soluble organomolybdenum friction modifiers worked best in severe, reciprocating sliding conditions. However, all friction modifier additive response was strongly affected by the other additives present in formulated engine oils. The friction performance of combinations of friction modifier additives was then explored. When two different friction modifiers additives were combined in solution, several possible outcomes were observed. The most common was for one of the additives to predominate, to give friction that was characteristic of that additive alone, while in some cases friction lay between the values produced by either additive on its own. In a few cases the additives behaved antagonistically so that the combination gave higher friction than either additive by itself. In a few cases true synergy was observed, where a combination of two additives produced lower friction in a g

  • Journal article
    Kanazawa Y, De Laurentis N, Kadiric A, 2019,

    STUDIES of Friction in Grease Lubricated Rolling Bearings Using Ball-on-Disc and Full Bearing Tests

    , Tribology Transactions, Pages: 1-28, ISSN: 1040-2004
  • Journal article
    Vidotto M, Botnariuc D, De Momi E, Dini Det al., 2019,

    A computational fluid dynamics approach to determine white matter permeability

    , Biomechanics and Modeling in Mechanobiology, Vol: 4, Pages: 1111-1122, ISSN: 1617-7940

    Glioblastomas represent a challenging problem with an extremely poor survival rate. Since these tumour cells have a highly invasive character, an effective surgical resection as well as chemotherapy and radiotherapy is very difficult. Convection-enhanced delivery (CED), a technique that consists in the injection of a therapeutic agent directly into the parenchyma, has shown encouraging results. Its efficacy depends on the ability to predict, in the pre-operative phase, the distribution of the drug inside the tumour. This paper proposes a method to compute a fundamental parameter for CED modelling outcomes, the hydraulic permeability, in three brain structures. Therefore, a bidimensional brain-like structure was built out of the main geometrical features of the white matter: axon diameter distribution extrapolated from electron microscopy images, extracellular space (ECS) volume fraction and ECS width. The axons were randomly allocated inside a defined border, and the ECS volume fraction as well as the ECS width maintained in a physiological range. To achieve this result, an outward packing method coupled with a disc shrinking technique was implemented. The fluid flow through the axons was computed by solving Navier–Stokes equations within the computational fluid dynamics solver ANSYS. From the fluid and pressure fields, an homogenisation technique allowed establishing the optimal representative volume element (RVE) size. The hydraulic permeability computed on the RVE was found in good agreement with experimental data from the literature.

  • Journal article
    Yu M, Evangelou S, Dini D, 2019,

    Position control of parallel active link suspension with backlash

    , IEEE Transactions on Industrial Electronics, Vol: 67, Pages: 4741-4751, ISSN: 0278-0046

    In this paper, a position control scheme for the novel Parallel Active Link Suspension (PALS) with backlash is developed to enhance the vehicle ride comfort and road holding. A PALS-retrofitted quarter car test rig is adopted, with the torque flow and backlash effect on the suspension performance analyzed. An elastic linear equivalent model of the PALS-retrofitted quarter car, which bridges the actuator position and the equivalent force between the sprung and unsprung masses, is proposed and mathematically derived, with both the geometry and backlash nonlinearities compensated. A position control scheme is then synthesized, with an outer-loop H∞ control for ride comfort and road holding enhancement and an inner-loop cascaded proportional-integral control for the reference position tracking. Experiments with the PALS-retrofitted quarter car test rig are performed over road cases of a harmonic road, a smoothed bump and frequency swept road excitation. As compared to a conventional torque control scheme, the newly proposed position control maintains the performance enhancement by the PALS, while it notably attenuates the overshoot in the actuator’s speed variation, and thereby it benefits the PALS with less power demand and less suspension deflection increment.

  • Journal article
    Zhan W, Rodriguez y Baena F, Dini D, 2019,

    Effect of tissue permeability and drug diffusion anisotropy on convection-enhanced delivery

    , Drug Delivery, Vol: 26, Pages: 773-781, ISSN: 1071-7544

    Although convection-enhanced delivery (CED) can successfully facilitate a bypass of the blood brain barrier, its treatment efficacy remains highly limited in clinic. This can be partially attributed to the brain anisotropic characteristics that lead to the difficulties in controlling the drug spatial distribution. Here, the responses of six different drugs to the tissue anisotropy are examined through a parametric study performed using a multiphysics model, which considers interstitial fluid flow, tissue deformation and interlinked drug transport processes in CED. The delivery outcomes are evaluated in terms of the penetration depth and delivery volume for effective therapy. Simulation results demonstrate that the effective penetration depth in a given direction can be improved with the increase of the corresponding component of anisotropic characteristics. The anisotropic tissue permeability could only reshape the drug distribution in space but has limited contribution to the total effective delivery volume. On the other hand, drugs respond in different ways to the anisotropic diffusivity. The large delivery volumes of fluorouracil, carmustine, cisplatin and doxorubicin could be achieved in relatively isotropic tissue, while paclitaxel and methotrexate are able to cover enlarged regions into anisotropic tissues. Results obtained from this study serve as a guide for the design of CED treatments.

  • Journal article
    Ayestarán Latorre C, Ewen JP, Gattinoni C, Dini Det al., 2019,

    Simulating surfactant-iron oxide interfaces: from density functional theory to molecular dynamics

    , The Journal of Physical Chemistry B, Vol: 123, Pages: 6870-6881, ISSN: 1520-6106

    Understanding the behaviour of surfactant molecules on iron oxide surfaces is important for many industrial applications. Molecular dynamics (MD) simulations of such systems have been limited by the absence of a force-field (FF) which accurately describes the molecule-surface interactions. In this study, interaction energies from density functional theory (DFT) + U calculations with a van der Waals functional are used to parameterize a classical FF for MD simulations of amide surfactants on iron oxide surfaces. The Original FF, which was derived using mixing rules and surface Lennard-Jones (LJ) parameters developed for nonpolar molecules, were shown to significantly underestimate the adsorption energy and overestimate the equilibrium adsorption distance compared to DFT. Conversely, the Optimized FF showed excellent agreement with the interaction energies obtained from DFT calculations for a wide range of surface coverages and molecular conformations near to and adsorbed on α-Fe2O3(0001). This was facilitated through the use of a Morse potential for strong chemisorption interactions, modified LJ parameters for weaker physisorption interactions, and adjusted partial charges for the electrostatic interactions. The Original FF and Optimized FF were compared in classical nonequilibrium molecular dynamics (NEMD) simulations of amide molecules confined between iron oxide surfaces. When the Optimized FF was employed, the amide molecules were pulled closer to the surface and the orientation of the headgroups was more similar to that observed in the DFT calculations compared to the Original FF. The Optimized FF proposed here facilitates classical MD simulations of anhydrous amide-iron oxide interfaces in which the interactions are representative of accurate DFT calculations.

  • Journal article
    Carpenter G, Bozorgi S, Vladescu S, Forte A, Myant C, Potineni R, Reddyhoff T, Baier Set al., 2019,

    A study of saliva lubrication using a compliant oral mimic

    , Food Hydrocolloids, Vol: 92, Pages: 10-18, ISSN: 0268-005X

    Due to ethical issues and the difficulty in obtaining biological tissues, it is important to find synthetic elastomers that can be used as replacement test media for research purposes. An important example of this is friction testing to understand the mechanisms behind mouthfeel attributes during food consumption (e.g. syrupy, body and clean finish), which requires an oral mimic. In order to assess the suitability of possible materials to mimic oral surfaces, a sliding contact is produced by loading and sliding a hemispherical silica pin against either a polydimethyl siloxane (PDMS), agarose, or porcine tongue sample. Friction is measured and elastohydrodynamic film thickness is calculated based on the elastic modulus of the samples, which is measured using an indentation method. Tests were performed with both saliva and pure water as the lubricating fluid and results compared to unlubricated conditions.PDMS mimics the tongue well in terms of protein adhesion, with both samples showing significant reductions in friction when lubricated with saliva versus water, whereas agarose showed no difference between saliva and water lubricated conditions. This is attributed to PDMS's OSi(CH3)2- group which provides excellent adhesion for the saliva protein molecules, in contrast with the hydrated agarose surface. The measured modulus of the PDMS (2.2 MPa) is however significantly greater than that of tongue (3.5 kPa) and agarose (66–174 kPa). This affects both the surface (boundary) friction, at low sliding speeds, and the entrained elastohydrodynamic film thickness, at high speeds.Utilising the transparent PDMS sample, we also use fluorescence microscopy to monitor the build-up and flow of dyed-tagged saliva proteins within the contact during sliding. Results confirm the lubricous boundary film forming nature of saliva proteins by showing a strong correlation between friction and average protein intensity signals (cross correlation coefficient = 0.87). This demonstrates

  • Journal article
    Puhan D, Wong J, 2019,

    Properties of Polyetheretherketone (PEEK) transferred materials in a PEEK-steel contact

    , Tribology International, Vol: 135, Pages: 189-199, ISSN: 0301-679X

    Polyetheretherketone (PEEK) is a high performance polymer that can be an alternative to metal for some moving components in unlubricated conditions. During rubbing, PEEK is transferred to the counterface. The formation and properties of PEEK transfer films on steel and sapphire are studied by in-situ observations of PEEK wear process, contact temperatures and triboemission, as well as FTIR and Raman spectroscopies ex situ. Our results suggest that frictional heating alone may not be sufficient to generate PEEK degradation observed in the transfer materials. Triboplasma observed during rubbing, together with the mechanical shear, may promote generations of radicals and degradation of PEEK, which subsequently influence the properties of PEEK transfer film and performance of polymer-metal tribopair.

  • Journal article
    Ferretti A, Giacopini M, Dini D, Fantoni Set al., 2019,

    Experimental measurement of roughness data and evaluation of Greenwood/Tripp parameters for the elastohydrodynamic analysis of a conrod small-end/piston pin coupling

    , SAE Technical Papers, Pages: 2019-24-0081-2019-24-0081, ISSN: 0148-7191
  • Journal article
    Hu S, Cao X, Reddyhoff T, Puhan D, Huang W, Shi X, Peng Z, Dini Det al., 2019,

    Three-dimensional printed surfaces inspired by bi-Gaussian stratified plateaus

    , ACS Applied Materials and Interfaces, Vol: 11, Pages: 20528-20534, ISSN: 1944-8244

    Wettability of artificial surfaces is attracting increasing attention for its relevant technological applications. Functional performance is often achieved by mimicking the topographical structures found in natural flora and fauna; however, surface attributes inspired by geological landscapes have so far escaped attention. We reproduced a stratified morphology of plateaus with a bi-Gaussian height distribution using a three-dimensional direct laser lithography. The plateau-inspired artificial surface exhibits a hydrophobic behavior even if fabricated from a hydrophilic material, giving rise to a new wetting mechanism that divides the well-known macroscopic Wenzel and Cassie states into four substates. We have also successfully applied the plateau-inspired structure to droplet manipulation.

  • Journal article
    Dawczyk J, Morgan N, Russo J, Spikes Het al., 2019,

    Film thickness and friction of ZDDP tribofilms

    , Tribology Letters, Vol: 67, ISSN: 1023-8883

    Tribofilm formation by several zinc dialkyl- and diaryldithiophosphate (ZDDP) solutions in thin film rolling-sliding conditions has been investigated. A primary, a secondary alkyl and a mixed alkyl ZDDP show similar rates of film formation and generate films typically 150 nm thick. Another secondary ZDDP forms a tribofilm much faster and the film is partially lost after extended rubbing. An aryl ZDDP forms a tribofilm much more slowly. The films all have a pad-like structure, characterised by flat pad regions separated by deep valleys. Three different techniques have been used to analyse the thickness and morphology of the tribofilms: spacer layer imaging (SLIM), scanning white light interferometry (SWLI) of the gold-coated film and contact mode atomic force microscopy (AFM). The SLIM method measures considerably thicker films than the other two techniques, probably because of lack of full conformity of a glass disc loaded against the rough tribofilm. No evidence of a highly viscous layer on top of the solid tribofilm is seen. SWLI and contact mode AFM measure similar film thicknesses. The importance of coating the tribofilm with a reflective layer prior to using SWLI is confirmed. As noted in previous work, the formation of a ZDDP tribofilm is accompanied by a marked shift in the Stribeck friction curve towards higher entrainment speed. For a given ZDDP this shift is found to correlate with the measured tribofilm roughness, proving that it results from the influence of this roughness on fluid entrainment in the inlet.

  • Journal article
    Sufian A, Knight C, O'Sullivan C, Van Wachem B, Dini Det al., 2019,

    Ability of a pore network model to predict fluid flow and drag in saturated granular materials

    , Computers and Geotechnics, Vol: 110, Pages: 344-366, ISSN: 0266-352X

    The local flow field and seepage induced drag obtained from Pore Network Models (PNM) is compared to Immersed Boundary Method (IBM) simulations, for a range of linear graded and bimodal samples. PNM were generated using a weighted Delaunay Tessellation (DT), along with the Modified Delaunay Tessellation (MDT) which considers the merging of tetrahedral Delaunay cells. Two local conductivity models are compared in simulating fluid flow in the PNM. The local pressure field was very accurately captured, while the local flux (flow rate) exhibited more scatter and sensitivity to the choice of the local conductance model. PNM based on the MDT clearly provided a better correlation with the IBM. There was close similarity in the network shortest paths, indicating that the PNM captures dominant flow channels. Comparison of streamline profiles demonstrated that local pressure drops coincided with the pore constrictions. A rigorous validation was undertaken for the drag force calculated from the PNM by comparing with analytical solutions for ordered array of spheres. This method was subsequently applied to all samples, and the calculated force was compared with the IBM data. Linear graded samples were able to calculate the force with reasonable accuracy, while the bimodal samples exhibited slightly more scatter.

  • Journal article
    Geng Z, Puhan D, Reddyhoff T, 2019,

    Using acoustic emission to characterize friction and wear in dry sliding steel contacts

    , Tribology International, Vol: 134, Pages: 394-407, ISSN: 0301-679X

    © 2019 Acoustic emission (AE) was recorded during tribological tests on 52,100 steel specimens under different loads. AE signals were transformed to the frequency domain using a Fast Fourier Transform and parameters such as power, RMS amplitude, mean frequency, and energy were analyzed and compared with friction coefficient and wear volume measurements. Results show that certain acoustic frequencies reflect friction while others reflect wear. If frequencies are chosen optimally, AE and friction signals are highly correlated (Pearson coefficients >0.8). SEM and Raman analysis reveal how plastic deformation and oxide formation affect friction, wear and AE simultaneously. AE recordings contains more information than conventional friction and wear volume measurements and are more sensitive to changes in mechanism. This all demonstrates AE's potential as a tool to monitor tribological behavior.

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