@article{Collini:2020:10.1016/j.fuel.2019.116927,
author = {Collini, H and Li, S and Jackson, MD and Agenet, N and Rashid, B and Couves, J},
doi = {10.1016/j.fuel.2019.116927},
journal = {Fuel},
pages = {1--16},
title = {Zeta potential in intact carbonates at reservoir conditions and its impact on oil recovery during controlled salinity waterflooding},
url = {http://dx.doi.org/10.1016/j.fuel.2019.116927},
volume = {266},
year = {2020}
}

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TY  - JOUR
AB  - It is well known that oil recovery from carbonate reservoirs can be increased by modifying the injected brine composition in a process ‘controlled salinity water-flooding’ (CSW). However, the mineral- to pore- scale processes responsible for improved oil recovery (IOR) during CSW remain ambiguous and there is no method to predict the optimum CSW composition for a given crude-oil-brine rock system. Here we report the first integrated experimental measurements of zeta potential and IOR during CSW obtained at reservoir conditions. The zeta potential is a measure of the electrical potential at mineral-brine and oil-brine interfaces and controls the electrostatic forces acting between these interfaces.We find that the measured zeta potential in clean samples saturated with formation brine is typically positive and becomes more negative with brine dilution irrespective of temperature. After aging and wettability alteration, the zeta potential changes and we suggest a more positive zeta potential indicates a positive zeta potential at the oil-brine interface and vice-versa. Injecting low salinity brine yields IOR when the oil-brine zeta potential is identified to be negative, but no response when it is identified to be positive, consistent with the hypothesis that IOR during CSW is caused by an increase in the repulsive electrostatic force acting between mineral-brine and oil-brine interfaces. We suggest that the optimum brine composition for IOR during CSW should be chosen to yield the largest change in zeta potential at the mineral-brine interface with opposing polarity to the oil-brine interface and can be determined using the experimental method reported here.
AU  - Collini,H
AU  - Li,S
AU  - Jackson,MD
AU  - Agenet,N
AU  - Rashid,B
AU  - Couves,J
DO  - 10.1016/j.fuel.2019.116927
EP  - 16
PY  - 2020///
SN  - 0016-2361
SP  - 1
TI  - Zeta potential in intact carbonates at reservoir conditions and its impact on oil recovery during controlled salinity waterflooding
T2  - Fuel
UR  - http://dx.doi.org/10.1016/j.fuel.2019.116927
UR  - http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000510603500104&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
UR  - https://www.sciencedirect.com/science/article/pii/S0016236119323208?via%3Dihub
UR  - http://hdl.handle.net/10044/1/93553
VL  - 266
ER  - 

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